Water vapor transport in a series of polyarylates (Record no. 40648)

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fixed length control field 01968nam a2200217Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625124640.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-6304
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245 10 - TITLE STATEMENT
Title Water vapor transport in a series of polyarylates
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Membrane Science, 181(2), p.199-212, 2001
520 3# - SUMMARY, ETC.
Summary, etc. Water vapor sorption and transport properties are presented for a series of polyarylates. The effect of making various structural changes in the polymer backbone has been studied, by comparing the transport properties to those of the base polymer bisphenol A isophthalate. All the polymers exhibit an upturn in the sorption isotherm at moderate to high activities, which in most cases is caused by plasticization of the polymer by water vapor. The response of water vapor to the structural changes is compared to that of the permanent gases reported previously for these materials. A good correlation is established between the diffusion and permeability coefficients and the fractional free volume. A similar behavior is seen in gases. However, the solubility coefficient, which decreases with increase in the fractional free volume, shows an opposite effect. Water vapor has the ability to hydrogen bond with itself and interact strongly with the polymer. In the case of solubility, the water vapor-polymer interaction plays an important role and overrides the effect of the increase in fractional free volume. The structural changes described here have similar effects on the permeation of water in a series of polysulfones reported earlier, as seen here for the polyarylates.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYARYLATES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYMER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PLASTICIZATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Kelkar, A.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Paul, D.R.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1eze6nQQFl8gVvFqdAvmGLtFGUxACHN3q/view?usp=drivesdk">https://drive.google.com/file/d/1eze6nQQFl8gVvFqdAvmGLtFGUxACHN3q/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-6304 25.06.2025 25.06.2025 Documentos solicitados