Polyisophthalamides with Heteroaromatic Pendent Rings: Synthesis, Physical Properties, and Water Uptake (Record no. 41965)

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control field 20250625124705.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-7641
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Title Polyisophthalamides with Heteroaromatic Pendent Rings: Synthesis, Physical Properties, and Water Uptake
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Polymer Science: Part A: Polymer Chemistry, 43(21), p.5300-5311, 2005
520 3# - SUMMARY, ETC.
Summary, etc. A set of novel aromatic polyamides containing pyridine pendent groups was prepared from aromatic diamines and new monomers that are 5-substituted derivatives of isophthalic acid bearing nicotinamide, isonicotinamide, or picolinamide groups. The polymers were obtained in high yield and high molecular weight by the phosphorylation method of polycondensation. They were characterized by spectroscopic and chromatographic methods and several of their properties were investigated. All of the polymers were soluble in polar aprotic solvents and gave films of good mechanical properties. Glass transition temperatures were higher than that of the reference polymer, poly(m-phenyleneisophthalamide)(IP-MPD), while the thermal resistance, defined by the initial decomposition temperature observed by thermogravimetry, was in the range 370-420 8C, lower by 30-70 8C than that of IP-MPD. The presence of a pendent pyridine group and an additional amide side group per repeat unit made the polymers essentially amorphous and greatly improved their abilities to absorb water in comparison with nonsubstituted polyamides. Water uptake values up to 15
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element COMPUTER MODELING
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Topical term or geographic name entry element MONOMERS
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Topical term or geographic name entry element POLYAMIDES
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Topical term or geographic name entry element STRUCTURE-PROPERTY RELATIONS
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Topical term or geographic name entry element SYNTHESIS
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Topical term or geographic name entry element THERMAL PROPERTIES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element WATER UPTAKE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ferreiro, J.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name De La Campa, J.G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lozano, A.E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name De Abajo, J.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1LpZ928E8zTTVm8BFTxOEDriJpFAHsV7_/view?usp=drivesdk">https://drive.google.com/file/d/1LpZ928E8zTTVm8BFTxOEDriJpFAHsV7_/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-7641 25.06.2025 25.06.2025 Documentos solicitados