Mass transport of direct methanol fuel cell species in sulfonated poly(ether ether ketone)membranes (Record no. 42071)

MARC details
000 -LEADER
fixed length control field 02249nam a2200301Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625124707.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-7749
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250602s9999 xx |||||s2 |||| ||und|d
245 10 - TITLE STATEMENT
Title Mass transport of direct methanol fuel cell species in sulfonated poly(ether ether ketone)membranes
490 0# - SERIES STATEMENT
Volume/sequential designation Electrochimica Acta, 51(18), p.3699-3706, 2006
520 3# - SUMMARY, ETC.
Summary, etc. Homogeneous membranes based on sulfonated poly(ether ether ketone)(sPEEK)with different sulfonation degrees (SD)were prepared and characterized. In order to perform a critical analysis of the SD effect on the polymer barrier and mass transport properties towards direct methanol fuel cell species, proton conductivity, water/methanol pervaporation and nitrogen/oxygen/carbon dioxide pressure rise method experiments are proposed. This procedure allows the evaluation of the individual permeability coefficients in hydrated sPEEK membranes with different sulfonation degrees. NafionR 112 was used as reference material. DMFC tests were also performed at 50 .C. It was observed that the proton conductivity and the permeability towards water, methanol, oxygen and carbon dioxide increase with the sPEEK sulfonation degree. In contrast, the SD seems to not affect the nitrogen permeability coefficient. In terms of selectivity, it was observed that the carbon dioxide/oxygen selectivity increases with the sPEEK SD. In contrast, the nitrogen/oxygen selectivity decreases. In terms of barrier properties for preventing the DMFC reactants loss, the polymer electrolyte membrane based on the sulfonated poly(ether ether ketone)with SD lower or equal to 71
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SULFONATED POLY(ETHER ETHER KETONE)(SPEEK)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NAFION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CONDUCTIVITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PERVAPORATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PRESSURE RISE METHOD
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PERMEABILITY COEFFICIENTS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DIRECT METHANOL FUEL CELL
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Silva, V.S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ruffmann, B.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Vetter, S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Boaventura, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mendesb, A.M.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1ZK2ukEbBEK2cWaGtAPo9RKWKQqQSxwGN/view?usp=drivesdk">https://drive.google.com/file/d/1ZK2ukEbBEK2cWaGtAPo9RKWKQqQSxwGN/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
Holdings
Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Shelving location Date acquired Total checkouts Full call number Date last seen Price effective from Koha item type
  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-7749 25.06.2025 25.06.2025 Documentos solicitados