In situ Raman spectroelectrochemical study of electrocatalytic oxidation of ascorbate at polyaniline- and sulfonated polyaniline-modified electrodes (Record no. 42370)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625124713.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-8059
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245 10 - TITLE STATEMENT
Title In situ Raman spectroelectrochemical study of electrocatalytic oxidation of ascorbate at polyaniline- and sulfonated polyaniline-modified electrodes
490 0# - SERIES STATEMENT
Volume/sequential designation Electrochimica Acta, 51(26), p.5761-5766, 2006
520 3# - SUMMARY, ETC.
Summary, etc. Electrocatalytic oxidation of ascorbate at electrodes, covered with polyaniline and sulfonated polyaniline, has been studied by in situ Raman spectroelectrochemistry with the green laser excitation (532 nm). Characteristic Raman features have been identified and their changes during electrooxidation of ascorbate have been analysed. It has been shown that an increase of ascorbate concentration causes an increase of the relative content of the reduced polyaniline form within the film. From this, it has been concluded that electrocatalytic oxidation of ascorbate proceeds within a polyaniline film rather than at an outer polyaniline/solution boundary, i.e. electrooxidation follows a redox-catalysis mechanism.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYANILINE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element RAMAN SPECTROSCOPY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SPECTROELECTROCHEMISTRY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTROCATALYSIS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ASCORBATE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ma¡Zeikienÿe,R.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Niaura,G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Malinauska, A.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1gtWBP6d207a1f-uH4w2h-NM903UvAKRh/view?usp=drivesdk">https://drive.google.com/file/d/1gtWBP6d207a1f-uH4w2h-NM903UvAKRh/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-8059 25.06.2025 25.06.2025 Documentos solicitados