Pt-Sn/C electrocatalysts for methanol oxidation synthesized by reduction with formic acid (Record no. 42421)

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control field MX-MdCICY
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control field 20250625124714.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-8112
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245 10 - TITLE STATEMENT
Title Pt-Sn/C electrocatalysts for methanol oxidation synthesized by reduction with formic acid
490 0# - SERIES STATEMENT
Volume/sequential designation Electrochimica Acta, 50(28), p.5496-5503, 2005
520 3# - SUMMARY, ETC.
Summary, etc. Carbon supported Pt.Sn alloy catalysts were prepared by reduction of Pt and Sn precursors with formic acid, and their electrocatalytic activity for methanol oxidation was compared with commercial Pt/C and Pt75Sn25/C electrocatalysts. By X-ray diffraction analysis it was found that the Pt lattice parameter increases with the addition of Sn, indicative of alloy formation. It was confirmed that Sn exhibits cocatalytic activity for CO oxidation. The onset potential for the methanol oxidation reaction of the Pt.Sn electrode was approximately 0.1V smaller than that on Pt both at room temperature and at 90 .C. The best performance in a direct methanol fuel cell was obtained using the Pt75Sn25/C alloy catalyst prepared by the formic acid method as the result of an optimal balance of Sn content, degree of alloying and metal particle size.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DIRECT METHANOL FUEL CELL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTROCATALYSIS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PT-SN ALLOY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element METHANOL OXIDATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Colmati, F.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Antolini, E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Gonzalez, E.R.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1f65K1E5WAmOkRQmUX5sAGiJUPHijIUmt/view?usp=drivesdk">https://drive.google.com/file/d/1f65K1E5WAmOkRQmUX5sAGiJUPHijIUmt/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-8112 25.06.2025 25.06.2025 Documentos solicitados