Effect of temperature on the mechanism of ethanol oxidation on carbon supported Pt, PtRu and Pt3Sn electrocatalysts (Record no. 42430)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 01947nam a2200241Ia 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | MX-MdCICY |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250625124714.0 |
| 040 ## - CATALOGING SOURCE | |
| Transcribing agency | CICY |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) | |
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) | B-8121 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 250602s9999 xx |||||s2 |||| ||und|d |
| 245 10 - TITLE STATEMENT | |
| Title | Effect of temperature on the mechanism of ethanol oxidation on carbon supported Pt, PtRu and Pt3Sn electrocatalysts |
| 490 0# - SERIES STATEMENT | |
| Volume/sequential designation | Journal of Power Sources, 157(1), p.98-103, 2006 |
| 520 3# - SUMMARY, ETC. | |
| Summary, etc. | The electrochemical oxidation of ethanol on carbon supported Pt, PtRu and Pt3Sn catalysts was studied in acid solutions at room temperature and in direct ethanol fuel cells (DEFC)in the temperature range 70.100 .C. In all the experiments, an enhancement of the activity for the ethanol oxidation was observed on the binary catalysts. In acid solution the improvement at low current densities was higher on PtRu than on Pt3Sn. In DEFC tests, at 70 .C the cells with PtRu and Pt3Sn showed about the same performance, while for T>70.C the cells with Pt3Sn as anode material performed better than those with PtRu as anode material. The apparent activation energy for ethanol oxidation on PtRu catalyst was lower than on Pt3Sn, particularly at high cell potentials, i.e. at low current densities. At low temperatures and/or low current densities, the positive effect of Ru oxides on the bifunctional mechanism determined the enhancement of activity for the ethanol oxidation reaction, while at high temperatures the positive effect of Sn alloying (enlarged lattice parameter)on CH3CH2OH adsorption and C.C cleavage prevails. |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | DIRECT ETHANOL FUEL CELL |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | ETHANOL OXIDATION |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | PTSN ALLOY |
| 650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical term or geographic name entry element | PTRU ALLOY |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Colmati, F. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Antolini, E. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Gonzalez, E.R. |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="https://drive.google.com/file/d/19L3ANjew2T1agWNLMwCIVy5dUdTgevpN/view?usp=drivesdk">https://drive.google.com/file/d/19L3ANjew2T1agWNLMwCIVy5dUdTgevpN/view?usp=drivesdk</a> |
| Public note | Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Clasificación local |
| Koha item type | Documentos solicitados |
| Lost status | Source of classification or shelving scheme | Damaged status | Not for loan | Collection | Home library | Current library | Shelving location | Date acquired | Total checkouts | Full call number | Date last seen | Price effective from | Koha item type |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Clasificación local | Ref1 | CICY | CICY | Documento préstamo interbibliotecario | 25.06.2025 | B-8121 | 25.06.2025 | 25.06.2025 | Documentos solicitados |