Characterization of the malate-aluminum(III)complex using 1H and 27Al NMR spectroscopy (Record no. 42964)

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control field 20250625124724.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-8661
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Title Characterization of the malate-aluminum(III)complex using 1H and 27Al NMR spectroscopy
490 0# - SERIES STATEMENT
Volume/sequential designation Magnetic Resonance in Chemistry, 45(6), p.518-521, 2007
520 3# - SUMMARY, ETC.
Summary, etc. Structural elucidation of a malate-aluminum(III)complex has been carried out using 1H and 27Al NMR spectroscopy. The 1H chemical shift perturbation clearly indicated the interaction between malate and Al(III)ion. The measurements of 27Al NMR and 1H-13C HSQC spectra demonstrated that the major form of a complex comprised two equivalent malate ions and two unequivalent Al(III)ions.With this constraint, an equilibrium geometry of the complex was proposed by a semi-empirical molecular orbital calculation.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NMR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element 1HNMR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element 27AL NMR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ALUMINUM(III)-BINDING
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MALATE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Tashiro, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Furihata, K.
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Personal name Fujimoto, T.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Machinami, T.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yoshimura, E.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1jYuWaFiGXzErpsRAwRqtLS77mcO3jMUD/view?usp=drivesdk">https://drive.google.com/file/d/1jYuWaFiGXzErpsRAwRqtLS77mcO3jMUD/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-8661 25.06.2025 25.06.2025 Documentos solicitados