Gas Barrier of Polystyrene Montmorillonite Clay Nanocomposites: Effect of Mineral Layer Aggregation (Record no. 43064)

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fixed length control field 02507nam a2200313Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625124726.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-8763
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245 10 - TITLE STATEMENT
Title Gas Barrier of Polystyrene Montmorillonite Clay Nanocomposites: Effect of Mineral Layer Aggregation
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Polymer Science: Part B: Polymer Physics, 45, p.1733-1753, 2007
520 3# - SUMMARY, ETC.
Summary, etc. Three polystyrene (PS)/clay hybrid systems have been prepared via in situ polymerization of styrene in the presence of unmodified sodium montmorillonite (Na- MMT)clay,MMTmodified with zwitterionic cationic surfactant octadecyldimethyl betaine (C18DMB)and MMT modified with polymerizable cationic surfactant vinylbenzyldimethyldodecylammonium chloride (VDAC). X-ray diffraction and TEM were used to probe mineral layer organization and to expose the morphology of these systems. The PS/Na- MMT composite was found to exhibit a conventional composite structure consisting of unintercalated micro and nanoclay particles homogeneously dispersed in the PS matrix. The PS/C18DMB-MMT system exhibited an intercalated layered silicate nanocomposite structure consisting of intercalated tactoids dispersed in the PS matrix. Finally, the PS/ VDAC-MMT system exhibited features of both intercalated and exfoliated nanocomposites. Systematic statistical analysis of aggregate orientation, characteristic width, length, aspect ratio, and number of layers using multiple TEM micrographs enabled the development of representative morphological models for each of the nanocomposite structures. Oxygen barrier properties of all three PS/clay hybrid systems were measured as a function of mineral composition and analyzed in terms of traditional Nielsen and Cussler approaches. A modification of the Nielsen model has been proposed, which considers the effect of layer aggregation (layer stacking)on gas barrier.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GAS BARRIER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GAS TRANSPORT MODEL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element LAYER AGGREGATES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MONTMORILLONITE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MORPHOLOGY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NANOCOMPOSITES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PERMEABILITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYSTYRENE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Nazarenko, S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Meneghetti, P.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Julmon, P.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Olson, B. G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Qutubuddin, S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1mRZaF8-dOl4JBKZrACOSvbAENa0HFZc-/view?usp=drivesdk">https://drive.google.com/file/d/1mRZaF8-dOl4JBKZrACOSvbAENa0HFZc-/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-8763 25.06.2025 25.06.2025 Documentos solicitados