Quantitative Structural Characterization of Polymer-Clay Nanocomposites and Discussion of an ''Ideal'' Microstructure, Leading to the Highest Mechanical Reinforcement (Record no. 43066)

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control field 20250625124726.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-8765
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245 10 - TITLE STATEMENT
Title Quantitative Structural Characterization of Polymer-Clay Nanocomposites and Discussion of an ''Ideal'' Microstructure, Leading to the Highest Mechanical Reinforcement
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Polymer Science: Part B: Polymer Physics, 45, p.1243-1251, 2007
520 3# - SUMMARY, ETC.
Summary, etc. Montmorillonite and other lamellar materials are very promising for reinforcing semicrystalline thermoplastics, especially if exfoliation is achieved. To understand the macroscopic properties of polymers filled with lamellar materials, it is unavoidable to characterize their structures. Parameters have to be determined such as the clay dispersion state, the orientations of the clay and of the polymer crystalline lamellae, and the interactions between the clay and the polymer matrix. Beyond the over-simple description as ''intercalated'' or ''exfoliated'' structures, we ropose a multiscale characterization of the state of exfoliation of the clay platelets based on the analysis of Optical Microscopy and Transmission Electron Microscopy images. The results have been confirmed by Small Angle X-Ray Scattering, which also gives pieces of information regarding the orientation of the clay platelets and of the polymer crystalline lamellae. Lastly, we propose the use of Dynamic Mechanical Analysis (DMA)as an indirect technique to probe the filler/matrix interfacial adhesion strength. In the light of these characterizations, we discuss a structure which is thought to lead to the highest reinforcement below and above Tg.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CLAY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MECHANICAL PROPERTIES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MICROSTRUCTURE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NANOCOMPOSITES
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Masenelli-Varlot, K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Vigier, G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Vermogen, A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Gauthier, C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Cavaille, J.Y.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/15UJDiUZEmgpMXgiBtP7179aD6eoUXOi0/view?usp=drivesdk">https://drive.google.com/file/d/15UJDiUZEmgpMXgiBtP7179aD6eoUXOi0/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-8765 25.06.2025 25.06.2025 Documentos solicitados