Polymer Crystallization in 25-nm Spheres (Record no. 43497)

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control field 20250625140608.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-9242
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Title Polymer Crystallization in 25-nm Spheres
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Volume/sequential designation Physical Review Letters, 84, p.4120-4123, 2000
520 3# - SUMMARY, ETC.
Summary, etc. Crystallization within the discrete spheres of a block copolymer mesophase was studied by timeresolved x-ray scattering. The cubic packing of microdomains, established by self-assembly in the melt, is preserved throughout crystallization by strong interblock segregation even though the amorphous matrix block is well above its glass transition temperature. Homogeneous nucleation within each sphere yields isothermal crystallizations which follow first-order kinetics, contrasting with the sigmoidal kinetics normally exhibited in the quiescent crystallization of bulk polymers.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Loo, Y.L.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Register, R.E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ryan, A.J.
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Uniform Resource Identifier <a href="https://drive.google.com/file/d/1l0y48unICQZsPsYUD97KDWqSB-otGmlU/view?usp=drivesdk">https://drive.google.com/file/d/1l0y48unICQZsPsYUD97KDWqSB-otGmlU/view?usp=drivesdk</a>
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