Identification of Betalains from Petioles of Differently Colored Swiss Chard (Beta vulgaris L. ssp. cicla [L.]Alef. Cv. Bright Lights)by High-Performance Liquid Chromatography-Electrospray Ionization Mass Spectrometry (Record no. 43714)

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control field MX-MdCICY
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control field 20250625140613.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-9464
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245 10 - TITLE STATEMENT
Title Identification of Betalains from Petioles of Differently Colored Swiss Chard (Beta vulgaris L. ssp. cicla [L.]Alef. Cv. Bright Lights)by High-Performance Liquid Chromatography-Electrospray Ionization Mass Spectrometry
490 0# - SERIES STATEMENT
Volume/sequential designation J. Agric. Food Chem., 52(10), p.2975-1981, 2004
520 3# - SUMMARY, ETC.
Summary, etc. The betalain pattern of differently colored Swiss chard (Beta vulgaris L. ssp. cicla [L.]Alef. cv. Bright Lights)was investigated for the first time. Nineteen betaxanthins and nine betacyanins were identified by RP-HPLC and positive ion electrospray mass spectrometry, co-injection experiments with semisynthetic reference compounds, and standards derived from authentic plant material, respectively. Histamine-betaxanthin and alanine-betaxanthin were found to be novel betaxanthins, which to the best of our knowledge have not been reported as natural compounds until now. Furthermore, tyramine-betaxanthin (miraxanthin III)and 3-methoxytyramine-betaxanthin, which to date were known only from families other than the Chenopodiaceae, were detected for the first time in colored Swiss chard. The betacyanin pattern of purple petioles was composed of betanin, isobetanin, betanidin, and isobetanidin. Although phyllocactin was present in only trace amounts, further acylated structures such as betanidin-monoferuloyl-5-O-â-diglucoside and lampranthin II, accompanied by their corresponding C15-epimers, were identified. In addition, quantification of betalains and CIE L*C*h° measurements were performed with the colored extracts to correlate the visual appearance with the respective pigment patterns. Besides the novel phytochemical findings, the present study is useful for the evaluation of betalainic Swiss chard as a potential coloring foodstuff
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CHENOPODIACEAE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BETA VULGARIS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element COLORED SWISS CHARD
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BETALAINS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BETAXANTHINS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ACYLATED BETACYANINS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element COLORING FOODSTUFF
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Kugler, F.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Stintzing, F.C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Carle, R.
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