Solution phase studies towards the synthesis of triarylamine oligomers using a germanium linker on a solid support (Record no. 44141)

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control field MX-MdCICY
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control field 20250625140621.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-9897
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Title Solution phase studies towards the synthesis of triarylamine oligomers using a germanium linker on a solid support
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Volume/sequential designation Tetrahedron Letters, 46(39):6717-6721, 2005
520 3# - SUMMARY, ETC.
Summary, etc. In this letter, we describe the iterative solution phase synthesis of a triarylamine trimer as proof of concept towards the synthesis of oligomeric materials by solid-phase synthesis. Our model system utilises the stability of germanium linkers to nucleophilic conditions to develop efficient steps towards oligomer synthesis via (i)selective deprotection of tert-butyl-dimethyl-silyl ether (OTBDMS)functionality, (ii)conversion to reactive trifluoromethanesulfonate (triflate)functionality and (iii)Suzuki cross-coupling reactions.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Anemian, R.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Cupertino, D.C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mackie, P.R.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yeates, S.G.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1clSs1xHeycK7NLGSjgmX9_FsP50t7SVa/view?usp=drivesdk">https://drive.google.com/file/d/1clSs1xHeycK7NLGSjgmX9_FsP50t7SVa/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-9897 25.06.2025 25.06.2025 Documentos solicitados