Ring-opening polymerization of lactones initiated by diphenylzinc-coinitiator systems (Record no. 44566)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625140629.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-10328
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
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245 10 - TITLE STATEMENT
Title Ring-opening polymerization of lactones initiated by diphenylzinc-coinitiator systems
490 0# - SERIES STATEMENT
Volume/sequential designation Polymer International, 42(6), p.1005-1009, 2003
520 3# - SUMMARY, ETC.
Summary, etc. Diphenylzinc, alone or in combination with water and butanone as coinitiators, was used as a polymerization initiator system for a variety of lactones at varying temperatures. The resulting data indicate that the course of the polymerization is greatly influenced by the lactone structure, as well as by the molar ratio of coinitiator to diphenylzinc. When used alone, diphenylzinc exhibited high activity as an initiator in ä-valerolactone polymerizations, although it was less efficient when used in the â-butyrolactone and the â-propiolactone polymerizations. Activity in the olymerization of â- lactones was increased by adding small amounts of butanone or water. It was also observed that the diphenylzinc-butanone combination was more effective than the diphenylzinc-water mixture in the polymerizations of â-butyrolactone and â-propiolactone.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DIPHENYLZINC
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element RING-OPENING POLYMERIZATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Ä-VALEROLACTONE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element Â-LACTONES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element O-ACYL CLEAVAGE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Vivas, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mejias, N.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Contreras, J.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1-nLyewPejF14j4s6YFU38a4JVGDhDp9t/view?usp=drivesdk">https://drive.google.com/file/d/1-nLyewPejF14j4s6YFU38a4JVGDhDp9t/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-10328 25.06.2025 25.06.2025 Documentos solicitados