Model interpretation of electrochemical impedance spectroscopy and polarization behavior of H2/CO mixture oxidation in polymer electrolyte fuel cells (Record no. 45350)

MARC details
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fixed length control field 01784nam a2200265Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625140644.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-11123
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
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245 10 - TITLE STATEMENT
Title Model interpretation of electrochemical impedance spectroscopy and polarization behavior of H2/CO mixture oxidation in polymer electrolyte fuel cells
490 0# - SERIES STATEMENT
Volume/sequential designation Electrochimica Acta, 46, p.4397-4405, 2001
520 3# - SUMMARY, ETC.
Summary, etc. A mathematical model is proposed based on electrode kinetics analysis for the oxidation of 2 porcent CO+H2 mixture in polymer electrolyte fuel cells. Successful simulation of the polarization curve and experimental impedance spectra for Pt/C electrode system confirm the validity of the model which shows that the impedance is strongly dependent on electrode potential. With the increase of potential, an inductive behavior will occur. It is believed that the appearance of this inductive pattern can be used as a criterion for the onset of CO oxidation by the coincidence of the potential at which inductive behavior occurs with the ignition potential for CO oxidation. The effects of change of CO oxidation rate constant and CO adsorption equilibrium constant on impedance pattern, as well as on CO surface coverage and Faradaic current are also delineated with the use of the proposed model.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element FUEL CELL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element IMPEDANCE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MODEL SIMULATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CO OXIDATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTROCATALYST
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Wang, X.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hsing, I.M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Leng, Y.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yue, P.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1RQC8tHlhNyhETKAxpWcKBPCO8-1lECdq/view?usp=drivesdk">https://drive.google.com/file/d/1RQC8tHlhNyhETKAxpWcKBPCO8-1lECdq/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-11123 25.06.2025 25.06.2025 Documentos solicitados