Irradiation effects on polycaprolactone (Record no. 45455)

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fixed length control field 01688nam a2200265Ia 4500
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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625140646.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-11228
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245 10 - TITLE STATEMENT
Title Irradiation effects on polycaprolactone
490 0# - SERIES STATEMENT
Volume/sequential designation Polymer, 26(1), p.50-54, 1985
520 3# - SUMMARY, ETC.
Summary, etc. The structure and some physical properties of ?-irradiated polycaprolactone (PCL), a semi-crystalline linear saturated polyester, were studied as function of the irradiation dose level. The critical dose level for gel formation is 26 Mrad and above this irradiation dose the number of scission events is similar to the number of crosslinking events. G.p.c. results show that the initial rather narrow molecular weight distribution gradually widens with increasing dose in the pre-gelation region. A significant difference between first and second d.s.c. scans of irradiated PCL is shown and explained. Scission and crosslinking reactions associated with the irradiation process occur preferentially in the non-ordered regions. Small irradiation doses, 2-5 Mrad, are shown to have a dramatic effect on the tensile elongation at break by converting ductile PCL samples into brittle materials.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element IRRADIATION EFFECTS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYCAPROLACTONE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GAMMA IRRADIATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GEL FORMATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Narkis, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Sibony-Chaouat, S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Siegmann, A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Shkolnik, S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Bell, J. P.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1ImRXGQmbX_oj-dPnUWVYvn3dydbpaHRp/view?usp=drivesdk">https://drive.google.com/file/d/1ImRXGQmbX_oj-dPnUWVYvn3dydbpaHRp/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-11228 25.06.2025 25.06.2025 Documentos solicitados