Sum Frequency Generation Vibrational Spectroscopic Studies on a Silane Adhesion-Promoting Mixture at a Polymer Interface (Record no. 45633)

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control field MX-MdCICY
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control field 20250625140650.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-11414
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Title Sum Frequency Generation Vibrational Spectroscopic Studies on a Silane Adhesion-Promoting Mixture at a Polymer Interface
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Volume/sequential designation Journal of Physics Chem. B, 110(2), p.914-918, 2006
520 3# - SUMMARY, ETC.
Summary, etc. Sum frequency generation (SFG)vibrational spectroscopy was used to probe the interface between poly- (ethylene terephthalate)with deuterated ethylene glycol subunits (d4-PET)and a silane adhesion-promoting mixture (SAPM)comprised of (3-glycidoxypropyl)trimethoxysilane (ç-GPS)and a methylvinylsiloxanol (MVS). Such a mixture has been found to improve the adhesion of an addition-curing silicone elastomer to a range of plastic and metal substrates. Our results demonstrated that at the interface between d4-PET and a SAPM with a ç-GPS/MVS ratio of 1:1 (w/w), the silane molecules not only segregated to the interface but also the methoxy headgroups likely adopted a greater net orientational order along the surface normal than at the d4-PET/ç-GPS interface. The effects of varying the silane/siloxane ratio and using different siloxane oligomers on interfacial structures were also examined. This study provides unique molecular-level insights into the prerequisite conditions for adhesion of curable silicone adhesives.
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Personal name Loch, C.L.
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Personal name Ahn, D.
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Personal name Chen, Z.
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Uniform Resource Identifier <a href="https://drive.google.com/file/d/15aWOeusWjaOTpAQrYgWlT65QjHiLS8rU/view?usp=drivesdk">https://drive.google.com/file/d/15aWOeusWjaOTpAQrYgWlT65QjHiLS8rU/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-11414 25.06.2025 25.06.2025 Documentos solicitados