Pulse polymerized polypyrrole electrodes for high energy density electrochemical supercapacitor (Record no. 45783)

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fixed length control field 01788nam a2200253Ia 4500
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control field MX-MdCICY
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control field 20250625140653.0
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Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-11567
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Title Pulse polymerized polypyrrole electrodes for high energy density electrochemical supercapacitor
490 0# - SERIES STATEMENT
Volume/sequential designation ElectroChemistry Communications, 10(2), p.268-272, 2008
520 3# - SUMMARY, ETC.
Summary, etc. A novel method of pulsed polymerization for pyrrole exhibiting highest capacitance and very high energy density polypyrrole supercapacitor is reported. Stable polypyrrole films with good electrochemical reversibility and high doping degree were obtained by applying ultra short on time current pulse for polymerization. Pulse on time plays an important role in controlling chain size and chain defects whereas pulse off time contributes in polymer conjugation and orientation. A regime of pulse on time is identified to yield highly capacitive and stable films for supercapacitor application. Very high specific capacitance of 400 F/g and an unexpectedly high energy density of 250 Wh/kg were obtained form pulsed polymerized ordered polypyrrole structures in acidic electrolyte. Stability tests performed on pulsed polymerized pPy electrode yield long cycling life up to 10,000 cycles at charge/discharge current density of 5 mA/cm2.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PULSE POLYMERIZATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTROCHEMICAL ELECTRODE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYPYRROLE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SUPERCAPACITOR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ENERGY DENSITY
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Sharma, R.K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Rastogi, A.C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Desu, S.B.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1Tp0Ra7ENNumnFLO-136yxFquLI24xZoE/view?usp=drivesdk">https://drive.google.com/file/d/1Tp0Ra7ENNumnFLO-136yxFquLI24xZoE/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-11567 25.06.2025 25.06.2025 Documentos solicitados