Development of Supported Bifunctional Electrocatalysts for Unitized Regenerative Fuel Cells (Record no. 45841)
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| fixed length control field | 02053nam a2200193Ia 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | MX-MdCICY |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250625140654.0 |
| 040 ## - CATALOGING SOURCE | |
| Transcribing agency | CICY |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) | |
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) | B-11625 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 250602s9999 xx |||||s2 |||| ||und|d |
| 245 10 - TITLE STATEMENT | |
| Title | Development of Supported Bifunctional Electrocatalysts for Unitized Regenerative Fuel Cells |
| 490 0# - SERIES STATEMENT | |
| Volume/sequential designation | Journal of The ElectroChemical Society, 149, p.1092-1099, 2002 |
| 520 3# - SUMMARY, ETC. | |
| Summary, etc. | Mixed metal catalysts containing Pt, Ir, Ru, Os, and Rh were synthesized on three different conductive oxide supports, Ebonex, which is a mixture of Ti4O7 and other phases, phase-pure microcrystalline Ti4O7 , and Ti0.9Nb0.1O2 , a doped rutile compound. Ebonex-supported catalysts were prepared as arrays and screened combinatorially for activity and stability as bifunctional oxygen reduction/water oxidation catalysts. The highest activity and stability was found in the Pt-Ru-Ir ternary region at compositions near Pt4Ru4Ir1 . X-ray near edge absorption spectra indicated a significant electronic interaction between the catalyst and the support, and a substantial increase in catalyst utilization was observed, even though the support surface areas were relatively low. Both Ebonex and Ti4O7 have short-lived electrochemical stability under conditions of oxygen evolution at 11.6 V vs. RHE in 0.5 M H2SO4 . Current at these supported catalysts gradually decreases, and the decrease is attributed to loss of electronic conductivity. Ebonex and Ti4O7 are also thermally oxidized in air at temperatures above 400°C. In contrast, Ti0.9Nb0.1O2 , which has a nondefective oxygen lattice, is quite resistant to electrochemical and thermal oxidation. Conditioning of Ti0.9Nb0.1O2-supported Pt4Ru4Ir1 at positive potentials had little effect on the activity of the catalyst. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Chen, G. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Bare, S.R. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Mallouk, T.E. |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="https://drive.google.com/file/d/1uyRiRiC4SWRTVgH5Kbj7VRv-z9iXWc9c/view?usp=drivesdk">https://drive.google.com/file/d/1uyRiRiC4SWRTVgH5Kbj7VRv-z9iXWc9c/view?usp=drivesdk</a> |
| Public note | Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Clasificación local |
| Koha item type | Documentos solicitados |
| Lost status | Source of classification or shelving scheme | Damaged status | Not for loan | Collection | Home library | Current library | Shelving location | Date acquired | Total checkouts | Full call number | Date last seen | Price effective from | Koha item type |
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| Clasificación local | Ref1 | CICY | CICY | Documento préstamo interbibliotecario | 25.06.2025 | B-11625 | 25.06.2025 | 25.06.2025 | Documentos solicitados |