Mass, charge and energy transport phenomena in a polymer electrolyte membrane (PEM)used in a direct methanol fuel cell (DMFC): Modelling and experimental validation of fluxes (Record no. 45940)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625140656.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-11724
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245 10 - TITLE STATEMENT
Title Mass, charge and energy transport phenomena in a polymer electrolyte membrane (PEM)used in a direct methanol fuel cell (DMFC): Modelling and experimental validation of fluxes
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Membrane Science, 276(1-2), p.272-285, 2006
520 3# - SUMMARY, ETC.
Summary, etc. The methanol and water crossover through the polymer electrolyte membrane (PEM)of the direct methanol fuel cell (DMFC)is analysed experimentally and theoretically. Crossover fluxes have been measured for different operating conditions using a miniplant with full online material balancing of all DMFC inlet and outlet material flows. The experimental data are compared to simulation results obtained from a one dimensional rigorous mathematical model of the DMFC. In this model, the main focus lies on the realistic description of mass and energy transport and physical properties of the PEM material. For mass transport, a model based on the generalised Maxwell-Stefan equations is formulated. To account for the very complex PEM behaviour (swelling with water/methanol as well as partition equilibria for both components between free liquid/gas phase and pores within the PEM), a Flory-Huggins activity model is used for the mobile species inside the PEM. The parameters of this model are determined from experiments. Membrane swelling is accounted for by an adaptive spatial discretisation in the model implementation.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYMER ELECTROLYTE MEMBRANE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NAFION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DIRECT METHANOL FUEL CELL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MODEL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MASS TRANSPORT
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Schultz, T.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Sundmacher, K.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/124SzFy1nNz_pj0bBO80gxM_ekO4Mz0Jx/view?usp=drivesdk">https://drive.google.com/file/d/124SzFy1nNz_pj0bBO80gxM_ekO4Mz0Jx/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-11724 25.06.2025 25.06.2025 Documentos solicitados