Redox poly[Ni(saldMp)] modified activated carbon electrode in electrochemical supercapacitors (Record no. 46157)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625140700.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-11944
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245 10 - TITLE STATEMENT
Title Redox poly[Ni(saldMp)] modified activated carbon electrode in electrochemical supercapacitors
490 0# - SERIES STATEMENT
Volume/sequential designation Electrochimica Acta, 55(20), p.6101-6108, 2010
520 3# - SUMMARY, ETC.
Summary, etc. The complex (2,2-dimethyl-1,3-propanediaminebis(salicylideneaminato))-nickel(II), [Ni(saldMp)], was oxidatively electropolymerized on activated carbon (AC)electrode in acetonitrile solution. The poly[Ni(saldMp)] presented an incomplete coated film on the surface of carbon particles of AC electrode by field emission scanning electron microscopy. The electrochemical behaviors of poly[Ni(saldMp)] modified activated carbon (PAC)electrode were evaluated in different potential ranges by cyclic voltammetry. Counterions and solvent swelling mainly occurred up to 0.6V for PAC electrode by the comparison of D1/2C values calculated from chronoamperometry experiments. Both the Ohmic resistance and Faraday resistance of PAC electrode gradually approached to those of AC electrode when its potential was ranging from 1.2V to 0.0 V. Galvanostatic charge/discharge experiments indicated that both the specific capacitance and energy density were effectively improved by the reversible redox reaction of poly[Ni(saldMp)] film under the high current density up to 10mAcm-2 for AC electrode. The specific capacitance of PAC electrode decreased during the first 50 cycles but thereafter it remained constant for the next 200 cycles. This study showed the redox polymer may be an attractive material in supercapacitors.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SUPERCAPACITOR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element REDOX POLYMER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ACTIVATED CARBON
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NONAQUEOUS SYSTEM
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYMERIZATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Gaoa, F.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Li, J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Zhang, Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Wang, X.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Kang, F.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1gc665WvEyKyftwAzjrwLHYsXjnpdt4LC/view?usp=drivesdk">https://drive.google.com/file/d/1gc665WvEyKyftwAzjrwLHYsXjnpdt4LC/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-11944 25.06.2025 25.06.2025 Documentos solicitados