Scanning electrochemical microscope (SECM)study of the relationship between proton concentration and electronic charge as a function of ionic strength during the oxidation of polyaniline (Record no. 46249)

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control field 20250625140702.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-12037
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245 10 - TITLE STATEMENT
Title Scanning electrochemical microscope (SECM)study of the relationship between proton concentration and electronic charge as a function of ionic strength during the oxidation of polyaniline
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Electroanalytical Chemistry, 379(1-2), p.399-406, 1994
520 3# - SUMMARY, ETC.
Summary, etc. The SECM has been used to investigate the influence of ionic strength on the ingress and egress of protons to and from a polyaniline (PANI)film. This was done in solutions containing 0.01 mol dm -3 HCI, with concentrations of NaC1 ranging from 0 to 0.5 mol dm 3, by measuring the steady-state faradaic current for H ÷ reduction on a 18 /~m diameter Pt microdisc located within few micrometres of the PANI film while cycling the potential of the film through the different oxidation states. The microelectrode response was calibrated using microdiscs of various sizes in different solutions of HCI, with and without the presence of supporting electrolyte. This investigation shows the influence of ionic strength on the film mechanism and in particular on the relationship between the behaviour of H + at the film Isolution interface and the behaviour of electrons at the film l electrode interface.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SCANNING ELECTROCHEMICAL MICROSCOPE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element IONIC STRENGTH
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element OXIDATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYANILINE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Troise Frank, M.H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Denuault, G.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1-noMSyDmpyq5M6ZmpLHf_rymDrXm0RY0/view?usp=drivesdk">https://drive.google.com/file/d/1-noMSyDmpyq5M6ZmpLHf_rymDrXm0RY0/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-12037 25.06.2025 25.06.2025 Documentos solicitados