Influence of oxidation state of polyaniline on physicochemical and transport properties of Nafion/polyaniline composite membrane for DMFC (Record no. 46254)

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fixed length control field 02451nam a2200277Ia 4500
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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625140702.0
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Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-12042
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245 10 - TITLE STATEMENT
Title Influence of oxidation state of polyaniline on physicochemical and transport properties of Nafion/polyaniline composite membrane for DMFC
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Membrane Science, 324(1-2), p.102-110, 2008
520 3# - SUMMARY, ETC.
Summary, etc. Herein,we report the chemical in situ synthesis ofNafion/polyanilinecompositemembranes, including the different intrinsic oxidation states of polyaniline (PANI)such as leucoemeraldine base (LEB), emeraldine salt (ES), and pernigraniline base (PB). To better understand the role of the oxidation states of PANI, the microstructure changes of the composite membraneswere extensively characterized by using the Fourier transform infrared (FT-IR)ATR, scanning electron microscopy (SEM), atomic force microscopy (AFM), small-angle X-ray scattering (SAXS), and wide-angle X-ray diffraction (WAXD). From an applicative point of view, direct methanol fuel cell (DMFC)proton conductivities and methanol permeabilities aswell as the DMFC performances of the composite membranes were evaluated by AC impedance spectroscopy, permeability experiments, and single cell experiments. In particular, Naf-ES membranes exhibited a higher selectivity and superior cell performances compared to those of other oxidation states as a result of the effective modification of morphology and physicochemical properties of Nafion. The morphology and physicochemical properties of composite membranes were controlled by specifically manipulating the interactions between Nafion and PANIs by means of the oxidation states of PANI. These findings provide a deeper understanding of the influence of the PANI oxidation states on the composite materials as well as a practical strategy to enhance the physical properties and performances of pristine Nafion.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NAFION/POLYANILINE COMPOSITE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element OXIDATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MORPHOLOGY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element TRANSPORT PROPERTY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DMFC
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Choi, B.G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Park, H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Suk Im, H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Kim, Y.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hi Hong, W.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1z28CK1339A_iRVyYQEfatWmUmwup97x9/view?usp=drivesdk">https://drive.google.com/file/d/1z28CK1339A_iRVyYQEfatWmUmwup97x9/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-12042 25.06.2025 25.06.2025 Documentos solicitados