Electrons from hydrogen (Record no. 46255)

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control field MX-MdCICY
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control field 20250625140702.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-12043
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Title Electrons from hydrogen
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Volume/sequential designation Chem. Commun., 21(23), p.3317-3325, 2009
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Summary, etc. The growing need for hydrogen-based fuel cells has driven research into hydrogenase (H2ase)-a natural enzyme that catalyses the extraction of electrons from H2 in water under ambient conditions. Unfortunately, the exact mechanism by which H2ase achieves this feat has remained a matter of some controversy until now, with many mechanisms being inconsistent with experimental data. Recently, however, we have been able to produce a successful catalytic mimic of H2ase that replicates key aspects of it. This paper begins with an overview of the research from many groups that preceded this discovery, followed by a detailed analysis of the key points that set our unique functional model apart-that is to say a proton-like ''hydride'' species, a surprisingly low-valent NiIRuI complex and the key insight that two molecules of H2 are required for electron extraction.
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Personal name Ogo, S.
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Uniform Resource Identifier <a href="https://drive.google.com/file/d/1TxkZjSIt0QKTUlvfgnkzYYWP8RW3hiI9/view?usp=drivesdk">https://drive.google.com/file/d/1TxkZjSIt0QKTUlvfgnkzYYWP8RW3hiI9/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-12043 25.06.2025 25.06.2025 Documentos solicitados