The useful properties of H2O as a ligand of a hydrogenase mimic (Record no. 46463)

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control field 20250625140706.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-12252
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Title The useful properties of H2O as a ligand of a hydrogenase mimic
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Volume/sequential designation Dalton Transactions, 39(9), p.2218-2225, 2010
520 3# - SUMMARY, ETC.
Summary, etc. This paper investigates the required properties of Ru-coordinated ligands of a Ni-Ru based hydrogenase mimic. A series of ligands, including MeCN, pyridine, H2O andOH- were coordinated to Ru, with H2O being the only ligand to promote H2-activation. In addition, a tethered pyridyl moiety was synthesised and found to completely inhibit H2-activation. We conclude, therefore, that H2O is the ideal ligand for this mimic as a result of both its mild basicity and the availability of two lone pairs for simultaneous binding to Ru and H2.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Zheng, C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Kim, K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Matsumoto, K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ogo, S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1pGrId8UuKOXfQZlOS2dNUbFpg-lN6vgV/view?usp=drivesdk">https://drive.google.com/file/d/1pGrId8UuKOXfQZlOS2dNUbFpg-lN6vgV/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-12252 25.06.2025 25.06.2025 Documentos solicitados