Thermal degradation of plasticized poly(3-hydroxybutyrate)investigated by DSC (Record no. 47696)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625153923.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-13497
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245 10 - TITLE STATEMENT
Title Thermal degradation of plasticized poly(3-hydroxybutyrate)investigated by DSC
490 0# - SERIES STATEMENT
Volume/sequential designation Polymer Degradation and Stability, 77, p.35-41, 2002
520 3# - SUMMARY, ETC.
Summary, etc. The thermal degradation of poly(3-hydroxybutyrate)(PHB)in the presence of two plasticizers (glycerol, glycerol triacetate)was investigated by differential scanning calorimetry (DSC). The thermal degradation was studied as a function of the annealing time, temperature and cooling rate after the thermal treatment. PHB thermal degradation proceeds by the random scission of the polymer chain. The presence of glycerol leads to a significant prodegradative effect on PHB presumably due to the alcoholysis reaction, while glycerol triacetate (triacetine)behaved as an almost inert additive from this point of view. Size exclusion chromatography (SEC)confirmed the results obtained by the DSC method. The data lead to the conclusion that DSC is a suitable method for estimation of PHB thermal degradation.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element THERMAL DEGRADATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DSC
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLY(3-HYDROXYBUTYRATE)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PLASTICIZER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element THERMAL TREATMENT
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ANNEALING
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SEC
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Janigova, I.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lacik, I.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chodak, I.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1sbPjWeqRwCLw28Cpl2jKNnc8ebjtLiPK/view?usp=drivesdk">https://drive.google.com/file/d/1sbPjWeqRwCLw28Cpl2jKNnc8ebjtLiPK/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-13497 25.06.2025 25.06.2025 Documentos solicitados