Modification of clay barriers with a cationic surfactant to improve the retention of pesticides in soils (Record no. 48616)

MARC details
000 -LEADER
fixed length control field 02671nam a2200277Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625153941.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-14426
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250602s9999 xx |||||s2 |||| ||und|d
245 10 - TITLE STATEMENT
Title Modification of clay barriers with a cationic surfactant to improve the retention of pesticides in soils
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Hazardous Materials, 139(2), p.363-372, 2007
520 3# - SUMMARY, ETC.
Summary, etc. In this work, the efficiency of reactive clay barriers in the immobilisation of organic pesticides in a sandy soil was studied. Reactive barriers were prepared by modification of montmorillonite, kaolinite and palygorskite clay minerals, and of a clayey soil with the cationic surfactant octadecyltrimethylammonium bromide (ODTMA). Percolation curves of the pesticides linuron, atrazine and metalaxyl of different hydrophobic character, were obtained in columns packed with a natural sandy soil with these barriers intercalated under saturated flowconditions. The cumulative curves in the unmodified soil indicated a leaching of pesticides greater than 85 percent of the total amount of compound added. After barrier intercalation, the breakthrough curves (BTC)indicated a dramatic decrease in the amounts of linuron leached in all columns and a significant modification of the leaching kinetics of atrazine and metalaxyl. Retardation factors, R, of the pesticides in the columns were significantly correlated with the organic matter content (OM)derived from the ODTMA of the organo clay/soil barriers (r2 .0.78). Significant correlations were also found between these R factors and the pore volume values corresponding to the maximum peaks of the BTCs (r2 = 0.83; p < 0.01)or the total volumes leached (r2 = 0.44; p < 0.05)for the pesticides atrazine and metalaxyl. The results obtained point to the interest in the use of reactive clay barriers for almost complete immobilisation of hydrophobic pesticides or for decreasing the leaching of moderately hydrophobic pesticides coming from point-like sources of pollution. These barriers would avoid the generation of elevated concentrations of these compounds in the soils due to their rapid washing.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PESTICIDES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element LEACHING
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SOIL COLUMN
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element REACTIVE BARRIER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ORGANO CLAY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ORGANO SOIL
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Rodríguez-Cruz,M.S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Sánchez-Martín, M.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Andrades, M.S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Sánchez-Camazano, M.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1-g2lIvkN1fyB6CZHcK2fYpbWBjHbj8BS/view?usp=drivesdk">https://drive.google.com/file/d/1-g2lIvkN1fyB6CZHcK2fYpbWBjHbj8BS/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
Holdings
Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Shelving location Date acquired Total checkouts Full call number Date last seen Price effective from Koha item type
  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-14426 25.06.2025 25.06.2025 Documentos solicitados