Nickel modified H-ZSM-5 catalysts (Record no. 48994)

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control field MX-MdCICY
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control field 20250625153948.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-14809
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Title Nickel modified H-ZSM-5 catalysts
490 0# - SERIES STATEMENT
Volume/sequential designation Applied Catalysis A: General, 114, p.295-311, 1994
520 3# - SUMMARY, ETC.
Summary, etc. Nickel containing H-ZSMJ catalysts were prepared by impregnation with nickel nitrate at pH 1.8 and 4.8. The catalysts were characterized by infrared spectroscopy of adsorbed carbon monoxide and ammonia, by temperature-programmed reduction as well as by chemisorption of hydrogen and oxygen. The conversion of n-hexane served as a catalytic test reaction. Impregnation at pH 1.8 leads to nickel ions exchange of Br@nsted sites in the channel system. These are hardly reducible and are not detectable by IR spectroscopy of adsorbed carbon monoxide. Aromatization is increased. This is explained by the presence of ionic nickel Lewis sites, active in dehydrogenation. With impregnation at pH 4.8, tetrameric nickel ions exist, not able to penetrate into the channels, and nickel is mainly located outside the channels as metallic nickel. The selectivity to aromatics is still higher. This should be due to the action of metallic nickel, which promotes the direct dehydrocyclization. The hydrogenolysis activity of metallic nickel is suppressed.
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Topical term or geographic name entry element ACIDITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element H-ZSM-5
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Topical term or geographic name entry element HEXANE CONVERSION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HIDDN POSITION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HYDROGEN/OXYGEN CHEMISORPTION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element INFRARED SPECTROSCOPY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NILH-ZSM-5
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element TEMPERATURE-PROGRAMMED REDUCTION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hoang, D.L.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Berndt, H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Miessner, H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Schreier, E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Vijlter, J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lieske, H.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/12Npn_K_LOkBqnHvl4MIlxbsrftd3ia1f/view?usp=drivesdk">https://drive.google.com/file/d/12Npn_K_LOkBqnHvl4MIlxbsrftd3ia1f/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-14809 25.06.2025 25.06.2025 Documentos solicitados