Chemical synthesis of highly electrically conductive polymers by control of oxidation potential (Record no. 49087)

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fixed length control field 01771nam a2200217Ia 4500
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control field MX-MdCICY
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control field 20250625153950.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-14903
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Title Chemical synthesis of highly electrically conductive polymers by control of oxidation potential
490 0# - SERIES STATEMENT
Volume/sequential designation Synthetic Metals, 41-43, p.3043-3048 , 1991
520 3# - SUMMARY, ETC.
Summary, etc. We report a new method for synthesizing highly electrically conducting polypyrrole and polythiophenes by control of the oxidation potential. The surface morphology and structural order of polypyrrole which was prepared by control of the oxidation potential have been investigated. A quite smooth, homogeneous and aligned fibril-like surface morphology was observed in the scanning electron micrographs of polypyrrole prepared by control of the oxidation potential, while those obtained by conventional chemical polymerization showed rough and globular structures. X- ray diffraction pattern of these two types of polypyrrole was also remarkably different. The high electrical conductivity and flexibility of polypyrrole obtained by controlling the oxidation potential may result from its homogeneous and ordered structure. The oxidation potential control technique was also applied to the polymerization of thiophene and its derivatives. Poly(3- methylthiophene)prepared by this technique exhibited electrical conductivity as high as 170 S/cm.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Whang, Y. E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Han, J. H.
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Personal name Nalwa, H. S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Watanabe, T.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Miyata, S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1Ts6vIrqXmm24G25TMc-zEBRPd0eL4Tdw/view?usp=drivesdk">https://drive.google.com/file/d/1Ts6vIrqXmm24G25TMc-zEBRPd0eL4Tdw/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-14903 25.06.2025 25.06.2025 Documentos solicitados