Experiments Directed Towards the Synthesis of Anthracyclinones. VIII* Functionalization of Hydroxyanthraquinones by Reductive Claisen Rearrangements (Record no. 49416)

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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-15235
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Title Experiments Directed Towards the Synthesis of Anthracyclinones. VIII* Functionalization of Hydroxyanthraquinones by Reductive Claisen Rearrangements
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Volume/sequential designation Australian Journal of Chemistry, 37(7), p.1511-1529, 1984
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Summary, etc. Gentle heating of allyloxyanthraquinones with sodium dithionite in dimethylformamide/water effects a rapid and controlled rearrangement to give high yields of 2-allylhydroxyanthraquinones. Starting from quinizarin, key intermediates for two synthetic routes to 4-demethoxydaunomycinone have been prepared from products by means of two such reductive Claisen rearrangements.
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Personal name Boddy, I.K.
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Personal name Boniface, P.J.
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Personal name Cambie, R.C.
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Personal name Craw, P.A.
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Personal name Huang, Z.
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Personal name Larsen, D.S.
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Personal name Mcdonald, H.
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Personal name Mcdonald, H.
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Personal name Woodgate, P.D.
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Uniform Resource Identifier <a href="https://drive.google.com/file/d/10jurCmOKEws90gfVOnf4f20bU4o4vvVf/view?usp=drivesdk">https://drive.google.com/file/d/10jurCmOKEws90gfVOnf4f20bU4o4vvVf/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-15235 25.06.2025 25.06.2025 Documentos solicitados