Dependence of the gas permeability of some polyimide isomers on their intrasegmental mobility (Record no. 50001)

MARC details
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fixed length control field 01782nam a2200313Ia 4500
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control field MX-MdCICY
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control field 20250625160139.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-15824
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245 10 - TITLE STATEMENT
Title Dependence of the gas permeability of some polyimide isomers on their intrasegmental mobility
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Membrane Science, 77(1), p.41-48, 1993
520 3# - SUMMARY, ETC.
Summary, etc. The polyimide PMDA-4,4'-ODA has a higher permeability and a lower selectivity toward H2, CO2, CH4, O2, and N2 than its isomer PMDA-3,3'-ODA. The differences in the gas permeability and selectivity are attributed to differences in the intrasegmental (rotational)mobility of PMDA-4,4'-ODA (the para-isomer)and of PMDA-3,3'-ODA (the meta-isomer). The phenyl rings in the para-isomer can rotate around their principal axis whereas such a rotation is not possible in the meta-isomer. This hypothesis is supported by dynamic mechanical analyses as well as by measurements of the CO2 diffusivity in the two isomers. Computer simulations indicate that rotation of the phenyl ring in the para-isomer is hindered by two larger rotational energy barriers of 4.0 and 2.4 kcal/mole, and two smaller ones of 1.3 kcal/mole. © 1993.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CARBON DIOXIDE
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Topical term or geographic name entry element COMPUTER SIMULATION
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Topical term or geographic name entry element DIFFUSION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HYDROGEN
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MECHANICAL PERMEABILITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element METHANE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MOLECULAR STRUCTURE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NITROGEN
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element OXYGEN
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYIMIDES
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mi, Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Stern, S.A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Trohalaki, S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/17ma_m0OSCBhVtTh5hIfsbRfyB2IjX34t/view?usp=drivesdk">https://drive.google.com/file/d/17ma_m0OSCBhVtTh5hIfsbRfyB2IjX34t/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-15824 25.06.2025 25.06.2025 Documentos solicitados