Thermal degradation of segmented polyurethanes (Record no. 50007)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625160140.0
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Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-15830
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245 10 - TITLE STATEMENT
Title Thermal degradation of segmented polyurethanes
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Applied Polymer Science, 51(6), p.1087-1095, 1994
520 3# - SUMMARY, ETC.
Summary, etc. Thermal degradation of polyurethane samples was studied by a thermogravimetric method. The effect of soft-segment length and soft-segment concentration on activation energy of the degradation process was measured. Three methods of calculation gave activation energies at different stages of the very complex weight loss process. It was shown that at initial stages of the weight loss the process was dominated by hard-segment degradation. Activation energy of the whole process calculated by the Ozawa-Flynn method did not offer clear insight into the structure-stability relationship of polyurethanes. The second method showed that activation energy of the initial stage of degradation increased with decrease in hard-segment length. The Flynn method of calculating activation energy produced fairly constant activation energy of the first 40 per cent degradation, at around 150 kJ/mol, for polymers in the C series. Generally, calculation of kinetic parameters of a complex degradation process as in polyurethanes gives results that are not easy to interpret. It has been shown qualitatively that polymers with higher soft-segment concentration display lower initial weight loss and higher onset temperatures of degradation.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DEGRADATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GRAVIMETRIC ANALYSIS
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Topical term or geographic name entry element MATHEMATICAL MODELS
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Topical term or geographic name entry element MOLECULAR STRUCTURE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element REACTION KINETICS
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Topical term or geographic name entry element THERMAL EFFECTS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element THERMOANALYSIS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element THERMODYNAMIC STABILITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ACTIVATION ENERGY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SEGMENTED POLYURETHANES
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Petrovic, Zoran S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Zavargo, Zoltan
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Flynn, Joseph H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Macknight, William J.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1SjrgcMwGYg0r9rBZ5NQseWIDeJK7f-ZT/view?usp=drivesdk">https://drive.google.com/file/d/1SjrgcMwGYg0r9rBZ5NQseWIDeJK7f-ZT/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-15830 25.06.2025 25.06.2025 Documentos solicitados