Degradation of medical-grade polyurethane elastomers: The effect of hydrogen peroxide in vitro (Record no. 50247)

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control field MX-MdCICY
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control field 20250625160144.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-16072
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245 10 - TITLE STATEMENT
Title Degradation of medical-grade polyurethane elastomers: The effect of hydrogen peroxide in vitro
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Biomedical Materials Research, 27(3), p.345-356, 1993
520 3# - SUMMARY, ETC.
Summary, etc. Treatment of Pellethane 2363-80A - a medical-grade poly(tetramethylene oxide)-based polyurethane elastomer - with 25 percent (w/w)hydrogen peroxide at 100°C for times ranging from 24 h to 336 h led to significant decreases in ultimate tensile properties and decreases in molecular weight, both at the surface and in the bulk. IR spectral changes were similar to those observed after degradation in vivo. Differential scanning calorimetry showed that hydrogen-peroxide-induced degradation was associated with greater order in the hard domain and greater mobility in the soft domain. Studies conducted with low-molecular-weight model compounds for the hard and soft segments confirmed that methylene groups adjacent to oxygen were susceptible toward oxidation. The extent of degradation of a series of commercial polyurethanes on treatment with hydrogen peroxide (25 percent, 24 h, 100°C)correlated well with their reported susceptibility to environmental stress cracking in vivo.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BIOMEDICAL EQUIPMENT
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELASTOMERS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HYDROGEN PEROXIDE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Meijs, G.F.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mccarthy, S.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Rizzardo, E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chen, Y.-C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chatelier, R.C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Brandwood, A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Schindhelm, K.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1JT7UPbN6M0kDu9f75x10uWKcdsN6cMEJ/view?usp=drivesdk">https://drive.google.com/file/d/1JT7UPbN6M0kDu9f75x10uWKcdsN6cMEJ/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-16072 25.06.2025 25.06.2025 Documentos solicitados