Synthesis of ZSM-5 zeolite with small crystal size and its catalytic performance for ethylene oligomerization (Record no. 50470)

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fixed length control field 02227nam a2200337Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625160148.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-16296
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245 10 - TITLE STATEMENT
Title Synthesis of ZSM-5 zeolite with small crystal size and its catalytic performance for ethylene oligomerization
490 0# - SERIES STATEMENT
Volume/sequential designation Zeolites, 14(8), p.643-649, 1994
520 3# - SUMMARY, ETC.
Summary, etc. ZSM-5 zeolites of SiO2 Al2O3 = 25 with a small crystal size were synthesized under various conditions in order to clarify a relationship between external surface area and catalytic performance, especially lifetime, for the oligomerization of ethylene to higher hydrocarbons of the gasoline range. The measurement of the external surface area, XRD patterns, and FTi.r. spectra of the resulting ZSM-5 zeolites suggested that their crystal grains were very fine. The shapes and sizes of the primary grains of the ZSM-5 zeolites were observed by means of a scanning electron microscopy with a magnification of 300,000. The crystal sizes were in the range of 30-50 nm. In the oligomerization of ethylene, a proton-type zeolite that was synthesized under a high molar ratio of OH SiO2 showed both high ethylene conversion and high gasoline range selectivity for three times longer on-stream time than those of other zeolites. The external surface area of the zeolite was also three times greater than those of other zeolites, which indicated that the lifetime of ZSM-5 zeolite in the oligomerization of ethylene depended on the external surface area or crystal size.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CATALYST SELECTIVITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CRYSTAL STRUCTURE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CRYSTALLIZATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CRYSTALS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ETHYLENE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GRAIN SIZE AND SHAPE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HYDROCARBONS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SCANNING ELECTRON MICROSCOPY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SURFACE MEASUREMENT
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SYNTHESIS (CHEMICAL)
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yamamura, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chaki, K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Wakatsuki, T.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Okado, H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Fujimoto, K.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1KXoGJXQmGDcpK7QmYrRoMD0BVXKNWKsY/view?usp=drivesdk">https://drive.google.com/file/d/1KXoGJXQmGDcpK7QmYrRoMD0BVXKNWKsY/view?usp=drivesdk</a>
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