Anomalous moisture diffusion in viscoelastic polymers: modeling and testing (Record no. 50471)

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control field MX-MdCICY
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control field 20250625160148.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-16297
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Title Anomalous moisture diffusion in viscoelastic polymers: modeling and testing
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Volume/sequential designation Journal of Applied Mechanics, 67(2), p.391-396, 2000
520 3# - SUMMARY, ETC.
Summary, etc. It is now well known that Fick's Law is frequently inadequate for describing moisture diffusion in polymers or polymer composites. Non-Fickian or anomalous diffusion typically occurs when the rates of diffusion and viscoelastic relaxation in a polymer are comparable, and the ambient temperature is below the glass transition temperature (Tg)of the polymer. As a result, it is necessary to take into account the time-dependent response of a polymer, analogous to viscoelastic relaxation of mechanical properties, in constructing such a model. In this paper, a simple yet robust methodology is proposed that would allow characterization of non-Fickian diffusion coefficients from moisture weight gain data for a polymer below its Tg. Subsequently, these diffusion coefficients are used for predicting moisture concentration profiles through the thickness of a polymer. Moisture weight gain data at different temperatures for an epoxy adhesive is employed to calibrate the model. Specimen thickness independence of the modeling parameters is established through comparison with test data. A finite element procedure that extends this methodology to more complex shapes and boundary conditions is also validated.
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Topical term or geographic name entry element BOUNDARY CONDITIONS
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Topical term or geographic name entry element COMPUTER SIMULATION
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Topical term or geographic name entry element DIFFUSION IN SOLIDS
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Topical term or geographic name entry element FINITE ELEMENT METHOD
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Topical term or geographic name entry element GLASS TRANSITION
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Topical term or geographic name entry element MATHEMATICAL MODELS
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Topical term or geographic name entry element MOISTURE
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Topical term or geographic name entry element NUMERICAL ANALYSIS
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Topical term or geographic name entry element RELAXATION PROCESSES
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Topical term or geographic name entry element TEMPERATURE
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Topical term or geographic name entry element VISCOELASTICITY
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Roy, S.
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Personal name Xu, W.X.
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Personal name Park, S.J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Liechti, K.M.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1HoOBpuXtb_u5XKKGTSArErkOKC7a4x79/view?usp=drivesdk">https://drive.google.com/file/d/1HoOBpuXtb_u5XKKGTSArErkOKC7a4x79/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-16297 25.06.2025 25.06.2025 Documentos solicitados