Structure/permeability relationships of polyimides with branched or extended diamine moieties (Record no. 50514)

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control field 20250625160149.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-16340
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Title Structure/permeability relationships of polyimides with branched or extended diamine moieties
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Volume/sequential designation Journal of Polymer Science Part B: Polymer Physics, 31(8), p.939-951, 1993
520 3# - SUMMARY, ETC.
Summary, etc. Mean permeability coefficients for CO2, O2, N2, and CH4 in seven types of 6FDA polyimides with branched or extended diamine moieties were determined at 35.0°C (95.0°F)and at pressures up to 10.5 atm (155 psia). In addition, solubility coefficients for CO2, O2, N2, and CH4 in six of these polyimides were determined at 35.0°C and at 6.8 atm (100 psia). Mean diffusion coefficients for the six gas/polyimide systems were calculated from the permeability and solubility data. The relationships between the chemical structure of the polyimides, some of their physical properties (glass transition temperature, mean interchain spacing, specific free volume), and their gas permeability, diffusivity, and solubility behavior are discussed. The 6FDA polyimides studied here exhibit a considerably lower selectivity for the CO2/CH4 and O2/N2 gas pairs than 6FDA polyimides with short and stiff aromatic diamines with comparable CO2 and O2 permeabilities.
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Topical term or geographic name entry element AMINES
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Topical term or geographic name entry element GASES
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Topical term or geographic name entry element MECHANICAL PERMEABILITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MOLECULAR STRUCTURE
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Topical term or geographic name entry element SEPARATION
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Personal name Stern, S.A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Liu, Y.
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Personal name Feld, W.A.
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Uniform Resource Identifier <a href="https://drive.google.com/file/d/1wEI7xhRNaT0_Gcjg5kqefTz3aQYPB6By/view?usp=drivesdk">https://drive.google.com/file/d/1wEI7xhRNaT0_Gcjg5kqefTz3aQYPB6By/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-16340 25.06.2025 25.06.2025 Documentos solicitados