Solution properties of pectin polysaccharides II. Conformation and molecular size of high galacturonic acid content isolated pectin chains (Record no. 50742)

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control field MX-MdCICY
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control field 20250625160154.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-16572
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Title Solution properties of pectin polysaccharides II. Conformation and molecular size of high galacturonic acid content isolated pectin chains
490 0# - SERIES STATEMENT
Volume/sequential designation Carbohydrate Polymers, 16(2), p.113-135, 1991
520 3# - SUMMARY, ETC.
Summary, etc. The solution properties of flax pectins and commercial pectins with high galacturonic acid content (AGA > 80 percent)were studied by low-angle laser-light scattering (LALLS), viscosity and Size Exclusion Chromatography (SEC)experiments performed in 0·2 M aq. NaCl. LALLS data were strongly affected by the presence of a small amount of high molecular weight superstructures. Molecularly dispersed pectin solutions could be obtained after complete removal of these high molecular weight particles by various procedures. The conformation of isolated pectin chains has been determined from the relationship between molecular weight, Mw, [?]and the distribution coefficient (Kd)measured on the Sephacryl 200/0·2 M NaCl chromatographic system. Analysis of the results, combined with a set of literature data, in terms of the known theories for rods and worm-like chains, gave values of 67 Å and 6 Å for the persistence length and the hydrodynamic diameter, respectively, of pectin in 0·2 M NaCl. These results suggest that pectin with a high galacturonate content behaves in NaCl solution like an extended coil with a similar conformation to the alginate chain. © 1991.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CARBOHYDRATES - MOLECULAR STRUCTURE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CHROMATOGRAPHIC ANALYSIS - SIZE EXCLUSION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element NATURAL POLYMERS - MOLECULAR WEIGHT
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SOLUTIONS - CHROMATOGRAPHIC ANALYSIS
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hourdet, D.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Muller, G.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1sWMuHfOFLB-am2WbxIRvqe1y-9hOsrzA/view?usp=drivesdk">https://drive.google.com/file/d/1sWMuHfOFLB-am2WbxIRvqe1y-9hOsrzA/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-16572 25.06.2025 25.06.2025 Documentos solicitados