Size exclusion chromatography of dextrans and pullulans with light scattering, viscosity and RI detection (Record no. 50760)

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control field 20250625160154.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-16590
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245 10 - TITLE STATEMENT
Title Size exclusion chromatography of dextrans and pullulans with light scattering, viscosity and RI detection
490 0# - SERIES STATEMENT
Volume/sequential designation Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, 69, p.274-275, 1993
520 3# - SUMMARY, ETC.
Summary, etc. With the introduction of multi-angle laser light scattering (MALLS)photometer, a potentially more powerful detection technique was made available. It was the objective of this work to characterize pullulans and dextrans in order to assess the performance of the size exclusion chromatograph with MALLS, viscosity and refractive index (RI)detectors. IT was anticipated that with the combination detectors, the performance of one detector could be effectively checked against that of the other. a SEC equipment was set up with light scattering, viscosity, and RI detectors. The ?Mw?'s by L.S. and universal calibration agreed very well with expected values for the low polydispersity pullulans and reasonably well for the broad MWD dextrans. The Rg (L.S.)agreed well with theoretical Rg for values above 10 nm, and scaling laws for whole polymers were in reasonable agreement with expected values. In conclusion, triple detection SEC proved to be a powerful and time saving technique for characterizing water soluble polymers absolutely, and confirming the values as well.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CHROMATOGRAPHIC ANALYSIS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DETECTORS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element LIGHT SCATTERING
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element REFRACTIVE INDEX
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SIZE EXCLUSION CHROMATOGRAPHY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element VISCOSITY MEASUREMENT
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Bahary, W.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hogan, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Jilani, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Aronson, M.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1QiLC7adzGyYi8rWSLbndmXMmf_bR7R6f/view?usp=drivesdk">https://drive.google.com/file/d/1QiLC7adzGyYi8rWSLbndmXMmf_bR7R6f/view?usp=drivesdk</a>
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