The photolytic release of copper from the copper penicillamine complex [Cu(II)6Cu(I)8(D-penicillamine)12Cl]5- (Record no. 50780)
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| fixed length control field | 01727nam a2200181Ia 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | MX-MdCICY |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250625160154.0 |
| 040 ## - CATALOGING SOURCE | |
| Transcribing agency | CICY |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) | |
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) | B-16610 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 250602s9999 xx |||||s2 |||| ||und|d |
| 245 10 - TITLE STATEMENT | |
| Title | The photolytic release of copper from the copper penicillamine complex [Cu(II)6Cu(I)8(D-penicillamine)12Cl]5- |
| 490 0# - SERIES STATEMENT | |
| Volume/sequential designation | Inorganica Chimica Acta, 152(4), p.219-222, 1988 |
| 520 3# - SUMMARY, ETC. | |
| Summary, etc. | The light sensitivity of CuPen ([Cu(II)6Cu(I)8(D-penicillamine)12Cl]5? was examined. The wavelength range of the photolytic activity was determined in the visible and near-ultraviolet region of the electromagnetic spectrum. No photolytic activity was observed above 450 nm. The quantum yield of copper release was measured between 450 nm and 250 nm and was found to increase from 0 to 0.1. A shoulder around 400 nm corresponding to electronic absorption and CD features was observed in the photo-action spectrum. Inhibition of formazan formation from nitroblue tetrazolium mediated by xanthine oxidase-generated superoxide was used to quantify the copper release as a result of the photolytic decomposition of CuPen. The influence of oxygen on the photolytic reaction was investigated by EPR and electronic absorption spectroscopy. In the absence of oxygen, visible light induces almost total bleaching. However, EPR reveals only slight changes in the spin concentration. Upon introduction of aerobic EDTA all of the copper is immediately oxidised to Cu(II). |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Deuschle, Ulrich |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Weser, Ulrich |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="https://drive.google.com/file/d/1u3uk9xxsefZql1VUUsd_26jjReU-DxTQ/view?usp=drivesdk">https://drive.google.com/file/d/1u3uk9xxsefZql1VUUsd_26jjReU-DxTQ/view?usp=drivesdk</a> |
| Public note | Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Clasificación local |
| Koha item type | Documentos solicitados |
| Lost status | Source of classification or shelving scheme | Damaged status | Not for loan | Collection | Home library | Current library | Shelving location | Date acquired | Total checkouts | Full call number | Date last seen | Price effective from | Koha item type |
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| Clasificación local | Ref1 | CICY | CICY | Documento préstamo interbibliotecario | 25.06.2025 | B-16610 | 25.06.2025 | 25.06.2025 | Documentos solicitados |