Synthesis of fluorine-containing natural gastrodin and its analogues (Record no. 51261)

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fixed length control field 01758nam a2200229Ia 4500
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control field MX-MdCICY
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control field 20250625160204.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-17098
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245 10 - TITLE STATEMENT
Title Synthesis of fluorine-containing natural gastrodin and its analogues
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Fluorine Chemistry, 46(3), p.367-374, 1990
520 3# - SUMMARY, ETC.
Summary, etc. Reactions of 2,3,4,6-tetra-O-acetyl-n-D_glucopyranosyl bromide (2)with p-hydroxybenzaldehyde, trifluoromethyl and fluoro substi- tuted aniline and 2-amino-6-fluorobenzoic acid gave l-O-(Pformyl- pheny1)-2,3,4,6-tetra-O-acetyl-(3-D-glucopyranoside (3), l-N-(m- trifluoromethylphenylamino)-2,3.4.6-tetra-O-acetyl-~~-D-glucopyra- noside (ra), l-N-(2-carboxyl-3-fluorophenyl)-2,3,4,6-tetra-O-acetyl -Is-D-glucopyranoside (4b)and 1-N-(p-fluorophenyl)-N-(2,3,4,6-tetra -0-acetyl-F-D-glucopyranoside (4~)respectively. 1-0-(perfluoro-2- propoxypropionyl)-O-benzyl-2,3,4,6-tetra-O-acetyl-~~-D-glucopyrano- side (7)and l-O-(m-trifluoromethylphenylaminobenzylidene)-2,3,4,6 -tetra-0-acetyl-\j-D-glucopyranoside (8)were also prepared in sub- sequent reactions. Conversion of the acetyl group to the hydroxyl group yielded the corresponding deprotected product. The compounds formed have been characterized by analysis, IR, 1~ and lgF NMR and mass spectroscopy. The influence of phase-transfer catalysts on the reactions is discussed.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GASTRODIN
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lin, Y. D.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Liang, Y. D.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Liang, S. G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Zhang, S. X.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Chi, C. S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/14-pZjntSy5yJlhd5WPfyzYdmkyL1Y95M/view?usp=drivesdk">https://drive.google.com/file/d/14-pZjntSy5yJlhd5WPfyzYdmkyL1Y95M/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-17098 25.06.2025 25.06.2025 Documentos solicitados