Viscoelastic relaxations and thermal properties of bacterial poly (3-hydroxybutyrate-co-3-hydroxyvalerate)and poly (3-hydroxybutyrate-co-4-hydroxybutyrate) (Record no. 51327)

MARC details
000 -LEADER
fixed length control field 02208nam a2200253Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625160205.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-17164
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250602s9999 xx |||||s2 |||| ||und|d
245 10 - TITLE STATEMENT
Title Viscoelastic relaxations and thermal properties of bacterial poly (3-hydroxybutyrate-co-3-hydroxyvalerate)and poly (3-hydroxybutyrate-co-4-hydroxybutyrate)
490 0# - SERIES STATEMENT
Volume/sequential designation International Journal of Biological Macromolecules, 12(2), p.112-117, 1990
520 3# - SUMMARY, ETC.
Summary, etc. 3-Hydroxybutyrate-3-hydroxyvalerate (3HB-3HV)as well as 3-hydroxybutyrate-4-hydroxybutyrate (3HB-4HB)copolyesters have been investigated by differential scanning calorimetry, thermogravimetric analysis and dynamic mechanical spectroscopy, over a wide range of compositions (0-95 mol percent 3HV; 0-82 mol percent 4HB). Both series of isolated copolyesters are partially crystalline at all compositions. Quenched samples show a glass transition that decreases linearly with increasing co-monomer molar fraction, more markedly when the co-monomer is 4HB. Above Tg, all copolyesters, rich in 3HB units, show a cold crystallization phenomenon followed by melting, while at the other end crystallization on heating is observed only in 3HB-3HV copolymers. The viscoelastic spectrum, strongly affected by thermal history, shows two relaxation regions; the glass transition, whose location depends on copolymer type and composition, and a secondary dispersion region at low temperatures (?130?80°C). The latter results from a water-related relaxation analogous to that of P(3HB)and, in 3HB-4HB copolymers, from another overlapping absorption peak centred at ?130°C, attributed to local motion of the methylene groups in the linear 4HB units.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLY(3-HYDROXYBUTYRATE-3-HYDROXYVALERATE)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLY(3-HYDROXYBUTYRATE-4-HYDROXYBUTYRATE)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BIOPOLYMERS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element VISCOELASTICITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element THERMAL PROPERTIES
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Scandola, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ceccorulli, G.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Doi, Y.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1R7-jScBophMcQYVtdhOAvfQW4DAhcebe/view?usp=drivesdk">https://drive.google.com/file/d/1R7-jScBophMcQYVtdhOAvfQW4DAhcebe/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
Holdings
Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Shelving location Date acquired Total checkouts Full call number Date last seen Price effective from Koha item type
  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-17164 25.06.2025 25.06.2025 Documentos solicitados