Structure of Tomatillidine (Record no. 51625)

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fixed length control field 01633nam a2200217Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625160211.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-17462
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
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245 10 - TITLE STATEMENT
Title Structure of Tomatillidine
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Organic Chemistry, 30(3), p.754-760, 1965
520 3# - SUMMARY, ETC.
Summary, etc. Tomatillidine (I)subjected to Wolff-Kishner reduction gave deoxotomatillidine (VII), which afforded dihydrodeoxotomatillidine (VIII)by catalytic hydrogenation. VIII was converted into 0,N-diacetyl-A22 dihydrodeoxotomatillidine, (X)by treatment with acetic anhydride, then into 3/3-acetoxy-26-acetylaminocholestan-22-one (XII), by acid hydrolysis. The latter (XII)yielded 3/3-acetoxybisnorallocholanic acid (XIV)by chromic acid oxidation. Selenium dehydrogenation of deoxotomatillidine (VII)afforded a 2,5-disubstituted pyridine derivative which aided in the elucidation of the structure of the basic moiety of the molecule. Mass spectral patterns of hexahydrotomatillidine (III), tetrahydrodeoxotomatillidine (XV), deoxotomatillidine (VII), tomatillidine (I), its O-acetyl derivative (la), and dihydrotomatillidine (II)and spectral data (ultraviolet, infrared, and n.m.r.)of O,N diacetyltomatillidine (VI)showed the location of the carbonyl group.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element TOMATILLIDINE
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Bianchi, Ennio
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Djerassi, Carl
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Budzikiewicz, Herbert
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Sato, Yoshio
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1eoe1p-RTYvQ7AlQPzMZX6z3TZkfIfGG_/view?usp=drivesdk">https://drive.google.com/file/d/1eoe1p-RTYvQ7AlQPzMZX6z3TZkfIfGG_/view?usp=drivesdk</a>
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-17462 25.06.2025 25.06.2025 Documentos solicitados