Transesterification of used cooking oil (UCO)catalyzed by mesoporous calcium titanate: Kinetic and thermodynamic studies (Record no. 52162)

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control field MX-MdCICY
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control field 20250625160221.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-18003
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245 10 - TITLE STATEMENT
Title Transesterification of used cooking oil (UCO)catalyzed by mesoporous calcium titanate: Kinetic and thermodynamic studies
490 0# - SERIES STATEMENT
Volume/sequential designation Energy Conversion and Management, 164, p.210-218, 2018
520 3# - SUMMARY, ETC.
Summary, etc. Due to the superior catalytic property of calcium oxide in biodiesel production via transesterification, it is necessary to modify such catalyst to retain the catalytic property while overcoming the disadvantages related to the catalyst application in the process. The present study focused on the kinetic and thermodynamic studies on the transesterification of used cooking oil (UCO)catalyzed by mesoporous calcium titanate (MCT). The experiments were performed at room temperature, 65?°C, and 100?°C. Among the various models being studied, the Pseudo First order is the best model to describe the reaction kinetic. Data analysis showed that the rate constants, k, varied in the range of 0.0233-0.058?s?1, while the activation energy, Ea was determined to be 21.25?kJ·mol?1. The following parameters were also obtained: ?24?kJ·mol?1 for enthalpy (?H), ?0.16?kJ·mol?1.K?1 for entropy (?S)and 25.62-35.70?kJ·mol?1 for Gibb's free energy (?G). The results showed that the reaction was exothermic (?H?<?0), and that the biodiesel oxidation reaction is non-spontaneous and endergonic in nature (?G?>?0). This study demonstrates the potential of MCT catalyst in promoting the conversion UCO into biodiesel with high quality fuel properties.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element KINETIC
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element THERMODYNAMIC
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element MESOPOROUS CATALYST
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element TRANSESTERIFICATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element BIODIESEL
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element USED COOKING OIL
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yahya, N. Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Ngadi, N.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Wong, S.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hassan, O.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1hxRPRr1mv22rGBgCAe8JxtCWwB8NSU9G/view?usp=drivesdk">https://drive.google.com/file/d/1hxRPRr1mv22rGBgCAe8JxtCWwB8NSU9G/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-18003 25.06.2025 25.06.2025 Documentos solicitados