Study of polypyrrole aging by XPS, FTIR and conductivity measurements. (Record no. 52496)

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fixed length control field 02183nam a2200289Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162410.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-18344
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
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245 10 - TITLE STATEMENT
Title Study of polypyrrole aging by XPS, FTIR and conductivity measurements.
490 0# - SERIES STATEMENT
Volume/sequential designation Polymer Degradation and Stability, 120, p.392-401, 2015
520 3# - SUMMARY, ETC.
Summary, etc. Five different polypyrroles (PPys)with four different oxidants, namely, FeCl3, FeCl3·6H2O, Fe2(SO4)3, and (NH4)2S2O8, were prepared by chemical oxidative polymerization and studied during aging. In the case of FeCl3, the anionic surfactant dodecylbenzenesulfonic acid (DBSA)was used as a co-dopant to improve the stability. The prepared PPys were aged (>400 days)in ambient air at a temperature of 24 ± 2 °C in our laboratory, where they were not directly exposed to the sun. A clear increase in the oxygen content could be seen on the surface of all the prepared samples. There was no significant difference between PPy prepared using FeCl3 and FeCl3·6H2O as oxidants. The incorporation of the anionic surfactant dodecylbenzenesulfonic acid into the PPy structure did not lead to a longer effective conjugation length but did lead to the superior stability of the prepared PPy in ambient air. PPy prepared with Fe2(SO4)3 and (NH4)2S2O8 showed inferior stability of electrical conductivity among the samples studied. The samples were characterized by X-ray photoelectron spectroscopy (XPS), Fourier transformed infrared spectroscopy (FTIR), and elemental analysis (EA), and the chemical changes during aging were confronted with measurements of the electrical conductivity.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLYPYRROLE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ELECTRICAL CONDUCTIVITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DEGRADATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element STABILITY
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element XPS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element FTIR
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CHEMICAL OXIDATIVE POLYMERIZATION
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Taba?Iarová, J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mi?Usík, M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Fedorko, P.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Omastova, M.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1TiEhkH80AQqxL_hbHiC2vqDhVwGhLwEA/view?usp=drivesdk">https://drive.google.com/file/d/1TiEhkH80AQqxL_hbHiC2vqDhVwGhLwEA/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-18344 25.06.2025 25.06.2025 Documentos solicitados