A novel green one-pot synthesis of biodiesel from Ricinus communis seeds by basic heterogeneous catalysis (Record no. 53292)

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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162425.0
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Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-19154
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245 10 - TITLE STATEMENT
Title A novel green one-pot synthesis of biodiesel from Ricinus communis seeds by basic heterogeneous catalysis
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Cleaner Production, 196, p.340-349, 2018
520 3# - SUMMARY, ETC.
Summary, etc. The production of biofuels from renewable biomass resources is an attractive way to mitigate CO2 emissions and alleviate the shortage of fossil fuels. A novel green one-pot synthesis of biodiesel from Ricinus communis seeds by basic heterogeneous catalysis is reported in this work. The direct transesterification (one-step process)of the seeds with methanol in the presence of homogeneous (HCl and NaOH)or heterogeneous (Na2ZrO3)catalysts was evaluated. Additionally, the comparison of the conventional (two-step process)transesterification against the direct transesterification reaction was analysed. The conventional transesterification of Ricinus communis oil with acidic (HCl/CH3OH, 5 percent v/v)and basic (NaOH/CH3OH, 5 percent w/w)homogeneous catalysts showed conversions of the fatty acid methyl esters (FAME)?>?97 percent at 6?h and 3?h, respectively. Moreover, direct transesterification was carried out using a basic Na2ZrO3 catalyst. The maximum FAME yield was 99.99 percent at 4?h of reaction time and 5?wt percent catalyst. Finally, Green Metrics Parameters of biodiesel showed that heterogeneous direct transesterification resulted in a seven times greener synthesis compared to conventional process. This novel heterogeneous one-step process is almost ten times less hazardous than the conventional process and five times less harmful than the homogeneous one-step reaction. No n-hexane is required for oil extraction. Thus, methanol as a reactant and as a solvent increased the greenness of the heterogeneous process, and the resulting biodiesel shows good purity and composition. In addition, no water is required to purify the biodiesel. According to these results, heterogeneous direct transesterification is a promising alternative for more sustainable, cleaner and efficient biodiesel production that is crucial to developing new technologies (by chemo-selectivity).
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DIRECT TRANSESTERIFICATION
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element FATTY ACID METHYL ESTER
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element RICINUS COMMUNIS SEED
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HETEROGENEOUS CATALYST
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HOMOGENEOUS CATALYST
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element GREEN METRIC PARAMETER
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Martínez, A.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Mijangos, G. E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Romero-Ibarra, I. C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Hernández-Altamirano, R.
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Personal name Mena-Cervantes, V. Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Gutiérrez, S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1sC5vjoEy_SMyGNQ7c5-_Ik33Byt6mgVN/view?usp=drivesdk">https://drive.google.com/file/d/1sC5vjoEy_SMyGNQ7c5-_Ik33Byt6mgVN/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-19154 25.06.2025 25.06.2025 Documentos solicitados