Organic/inorganic hybrid pigments from flavylium cations and palygorskite (Record no. 53497)

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fixed length control field 02249nam a2200301Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162429.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-19366
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245 10 - TITLE STATEMENT
Title Organic/inorganic hybrid pigments from flavylium cations and palygorskite
490 0# - SERIES STATEMENT
Volume/sequential designation Applied Clay Science, 162, p.478-486, 2018
520 3# - SUMMARY, ETC.
Summary, etc. Features such as color, brightness and fluorescence are extremely important in applications of pigments. Hybrid materials inspired by the ancient Maya Blue pigment are a promising alternative to improve the properties and applicability of natural and synthetic dyes. In this work, we report the preparation, photophysical properties, and stability of several fluorescent hybrid pigments based on flavylium cations (FL)adsorbed on palygorskite (PAL). Five flavylium cations were investigated, viz., the 3?,4?,7-trimethoxyflavylium (FL1), 7-hydroxy-4?-methoxy-flavylium (FL2), 7-hydroxy-4-methylflavylium (FL3), 5,7-dihydroxy-4-methylflavylium (FL4)and 7-methoxy-4-methylflavylium (FL5)cations. Only FL1 and FL2, without a methyl substituent at the 4-position that could hinder inclusion in palygorskite channels, adsorbed strongly on PAL, producing fluorescent hybrid pigments with attractive colors. The spectroscopic and fluorescence properties of the FL1/PAL and FL2/PAL hybrid pigments were characterized. The color of the adsorbed dyes was somewhat more resistant to changes in external pH, photochemical stability was maintained and the thermal lability was markedly improved in the FL/PAL hybrid pigments, pointing to flavylium cations as promising chromophores for the development of fluorescent hybrid pigments with attractive colors.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element FLUORESCENT HYBRID PIGMENTS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PALYGORSKITE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element DYES
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CLAYS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element FLAVYLIUM CATIONS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element COLOR
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Silva, G. T. M.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Silva, C. P.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Gehlen, M. H.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Oake, J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Bohne, C.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Quina, F. H.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1UapRxGIdEcUNgmGx9KJsiSMmzaQ-pDcC/view?usp=drivesdk">https://drive.google.com/file/d/1UapRxGIdEcUNgmGx9KJsiSMmzaQ-pDcC/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-19366 25.06.2025 25.06.2025 Documentos solicitados