Electroreduction of nitrogen at almost 100 percent current-to-ammonia efficiency (Record no. 53635)
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| fixed length control field | 02179nam a2200241Ia 4500 |
| 003 - CONTROL NUMBER IDENTIFIER | |
| control field | MX-MdCICY |
| 005 - DATE AND TIME OF LATEST TRANSACTION | |
| control field | 20250625162432.0 |
| 040 ## - CATALOGING SOURCE | |
| Transcribing agency | CICY |
| 090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN) | |
| Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) | B-19510 |
| 008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION | |
| fixed length control field | 250602s9999 xx |||||s2 |||| ||und|d |
| 245 10 - TITLE STATEMENT | |
| Title | Electroreduction of nitrogen at almost 100 percent current-to-ammonia efficiency |
| 490 0# - SERIES STATEMENT | |
| Volume/sequential designation | Nature, https://doi.org/10.1038/s41586-022-05108-y, 2022 |
| 520 3# - SUMMARY, ETC. | |
| Summary, etc. | Beyond its use in the fertiliser and chemical industries1, ammonia is currently seen as a potential replacement for carbon-based fuels and as a carrier for worldwide transportation of renewable energy2. Implementation of this vision requires transformation of the existing fossil fuel based technology for NH3 production3 to a simpler, scale-flexible technology, such as the electrochemical lithium-mediated nitrogen reduction reaction (Li-NRR)3,4. This provides a genuine pathway from N2 to ammonia, yet is hampered by limited yield rates and efficiencies4-12. Here we investigate the role of the electrolyte in this reaction and present a high-efficiency, robust process enabled by compact ionic layering in the electrode-electrolyte interfacial region. The interface is generated by a high-concentration imide-based lithium salt electrolyte, enabling stabilised ammonia yield rates of 150±20 nmol s-1 cm-2 and current-to-ammonia efficiency closely approaching 100 percent. The ionic assembly formed at the electrode surface suppresses electrolyte decomposition and supports stable N2 reduction. Our study highlights the interrelation between the performance of the Li-NRR and the physicochemical properties of the electrode-electrolyte interface. We anticipate that these findings will guide the development of a robust, high-performance process for sustainable ammonia production. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Du, H. L. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Chatti, M. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Hodgetts, R. Y. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Cherepanov, P. V. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Nguyen, C. K. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Matuszek, K. |
| 700 12 - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Simonov, A. N. |
| 856 40 - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | <a href="https://drive.google.com/file/d/14Vs8bSc0Nsg-Fkbn6BVrRZHdp2Pgw55l/view?usp=drivesdk">https://drive.google.com/file/d/14Vs8bSc0Nsg-Fkbn6BVrRZHdp2Pgw55l/view?usp=drivesdk</a> |
| Public note | Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Source of classification or shelving scheme | Clasificación local |
| Koha item type | Documentos solicitados |
| Lost status | Source of classification or shelving scheme | Damaged status | Not for loan | Collection | Home library | Current library | Shelving location | Date acquired | Total checkouts | Full call number | Date last seen | Price effective from | Koha item type |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Clasificación local | Ref1 | CICY | CICY | Documento préstamo interbibliotecario | 25.06.2025 | B-19510 | 25.06.2025 | 25.06.2025 | Documentos solicitados |