Aspects of Interfacial Structure of Silane Coupling Agents in Particulate-Filled Polymer Composites and the Reinforcement Effect: A Critical Review (Record no. 54062)

MARC details
000 -LEADER
fixed length control field 02732nam a2200289Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162440.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-19957
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250602s9999 xx |||||s2 |||| ||und|d
245 10 - TITLE STATEMENT
Title Aspects of Interfacial Structure of Silane Coupling Agents in Particulate-Filled Polymer Composites and the Reinforcement Effect: A Critical Review
490 0# - SERIES STATEMENT
Volume/sequential designation Reviews of Adhesion and Adhesives, 3(2), p.188-215, 2015
520 3# - SUMMARY, ETC.
Summary, etc. In order to form an effective interphase in a polymer composite, the preparation and characterization of silane structure on particle surface and in the interfacial layer in the composite are reviewed. The polycondensation of silane is affected by the concentration and pH of silane solution and the pH of inorganic particle. Pulsed 1H nuclear magnetic resonance (pulsed NMR)analysis is useful to characterize the structure of silane layer on the particle surface. It is found that the linear chain structure formed from dialkoxy type silane is flexible, whereas the network structure formed from trialkoxy type silane is rigid. To form an effective interphase, the linear chain structure formed from dialkoxy type is more useful than the network structure formed from trialkoxy type in the silica-filled rubber composites. The pre-treatment method and the integral blend method are compared in the silica-filled rubber composites. As a result, the dialkoxy type is found to be suitable for the pre-treatment method, whereas the trialkoxy type is suitable for the integral blend method. In the pre-treatment method, the linear silane chains form entanglements with the rubber chains in the interfacial region and improve the reinforcement effect. In the integral blend of trialkoxy type, the formation of the silane network and the entanglement proceed simultaneously during the preparation process and a well-entangled interfacial region is formed. Pulsed NMR analysis for the silica-filled unvulcanized rubber composites is useful to analyze the interfacial layer in the composites. The surface treatment of CaCO3 with a mixture of amino and mercapto functional silanes is found to be useful to improve the reinforcement effect in rubber/CaCO3 composites.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SILANE COUPLING AGENT
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element SURFACE TREATMENT
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element INTEGRAL BLEND
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element INTERPHASE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element COMPOSITE
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PULSED NMR
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Nakamura, Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Yamazaki, R.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Shitajima, K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Karyu, N.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Fujii, S.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1xYcULCi54AI7TxNA19Bo3FJCBo6B--tc/view?usp=drivesdk">https://drive.google.com/file/d/1xYcULCi54AI7TxNA19Bo3FJCBo6B--tc/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
Holdings
Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Shelving location Date acquired Total checkouts Full call number Date last seen Price effective from Koha item type
  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-19957 25.06.2025 25.06.2025 Documentos solicitados