Thermal degradation of polypropylene (Record no. 54072)

MARC details
000 -LEADER
fixed length control field 02047nam a2200193Ia 4500
003 - CONTROL NUMBER IDENTIFIER
control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162440.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
090 ## - LOCALLY ASSIGNED LC-TYPE CALL NUMBER (OCLC); LOCAL CALL NUMBER (RLIN)
Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-19967
008 - FIXED-LENGTH DATA ELEMENTS--GENERAL INFORMATION
fixed length control field 250602s9999 xx |||||s2 |||| ||und|d
245 10 - TITLE STATEMENT
Title Thermal degradation of polypropylene
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Polymer Science, 56(164), p.485-499, 1962
520 3# - SUMMARY, ETC.
Summary, etc. The molecular weight distributions of polypropylene samples subjected to various degrees of thermal degradation were experimentally determined and compared with those expected theoretically for random scission of the polymer chains. The comparison demonstrated that the chain breakage is predominately random and also indicates that current methods of determining molecular weight distributions are adequate for use in evaluating hypothesized degradation mechanisms. In terms of the free radical depolymerization theory, intermolecular transfer of the radical is the dominant process. A curve relating the degree of degradation to the intrinsic viscosity was obtained from calculations based upon a random degradation. With this curve, intrinsic viscosities measured as a function of degradation time could be used to obtain the time dependence of the degree of degradation. The observed degradation rates could not be described by a simple process in which the rate of bond rupture was proportional to the number of bonds present. Neither a similar process involving two bond types nor a dependence of the free radical diffusion rate upon the degree of degradation was by itself a satisfactory basis for interpreting the kinetics. The activation energy estimated for the polypropylene degradation at 250-300°C. was not significantly different from that determined by volatilization measurements at higher temperatures.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Davis, T. E.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Tobias, R. L.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Peterli, E. B.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1kzp5IHlHLeQnoeXQxQ1anb7fiw0yky3-/view?usp=drivesdk">https://drive.google.com/file/d/1kzp5IHlHLeQnoeXQxQ1anb7fiw0yky3-/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
Holdings
Lost status Source of classification or shelving scheme Damaged status Not for loan Collection Home library Current library Shelving location Date acquired Total checkouts Full call number Date last seen Price effective from Koha item type
  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-19967 25.06.2025 25.06.2025 Documentos solicitados