Numerical validation of direct ethanol fuel cell operating at high temperature (Record no. 54195)

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fixed length control field 01890nam a2200253Ia 4500
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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162442.0
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Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-20091
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245 10 - TITLE STATEMENT
Title Numerical validation of direct ethanol fuel cell operating at high temperature
490 0# - SERIES STATEMENT
Volume/sequential designation Ionics, https://doi.org/10.1007/s11581-022-04852-5, 2022
520 3# - SUMMARY, ETC.
Summary, etc. In the present work, a three-dimensional steady-state model was developed to analyze the performance of high-temperature direct ethanol fuel cell (HT-DEFC)based on polybenzimidazole (PBI)electrolytes. A non-isothermal model of a HT-DEFC setup using a PBI/H3PO4 membrane was employed using computational fluid dynamics (CFD). This work is aiming at a validation of experimental data of HT-DEFC prototypes based on the simulation of polarization curves. The model predicts the mole concentration of H3PO4, heat and current density distributions, as well as mass fraction ethanol during operation at 180 °C. The heat transfer model was coupled to the electrochemical and mass transport, allowing that a particular heating configuration was investigated considering the temperature distribution on the PBI membrane. We have found that temperature and relative humidity (RH)are mostly related to PBI properties resulting from H3PO4 lixiviation and conductivity decreasing as well as ethanol crossover strongly interferes on the oxygen reduction reaction (ORR)rate, leading to poor HT-DEFC performance.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element HT-DEFC
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PBI
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element CFD
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element PHOSPHORIC ACID
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ETHANOL
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Panesi, A. R. Q.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Silva, R. P.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Santiago, E
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1bOU_Td8w8HzIvIuxGdhOn1UksNoYpiG2/view?usp=drivesdk">https://drive.google.com/file/d/1bOU_Td8w8HzIvIuxGdhOn1UksNoYpiG2/view?usp=drivesdk</a>
Public note Para ver el documento ingresa a Google con tu cuenta: @cicy.edu.mx
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Source of classification or shelving scheme Clasificación local
Koha item type Documentos solicitados
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-20091 25.06.2025 25.06.2025 Documentos solicitados