N3-butyl imidazolium-based anion exchange membranes blended with Poly (vinyl alcohol)for alkaline water electrolysis (Record no. 54520)

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fixed length control field 02515nam a2200277Ia 4500
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control field MX-MdCICY
005 - DATE AND TIME OF LATEST TRANSACTION
control field 20250625162448.0
040 ## - CATALOGING SOURCE
Transcribing agency CICY
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Classification number (OCLC) (R) ; Classification number, CALL (RLIN) (NR) B-20428
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Title N3-butyl imidazolium-based anion exchange membranes blended with Poly (vinyl alcohol)for alkaline water electrolysis
490 0# - SERIES STATEMENT
Volume/sequential designation Journal of Membrane Science, 611, p.118355, 2020
520 3# - SUMMARY, ETC.
Summary, etc. Blended membranes composed of a series of N3-butyl-substituted imidazolium-based poly(1-vinyl-3-imidazole-co-styrene)(PIS), prepared via radical polymerization, and poly(vinyl alcohol)(PVA), were used as anion exchange membranes (AEM)for alkaline water electrolysis (AWE). PISPVAx blend membranes (where x denotes the ratio of imidazolium group and styrene in PIS being 4:6, 3:7, and 2:8)were doped with 6 M KOH solution to prepare OH? conductive AEMs and their thermal and mechanical properties, chemical stabilities, and hydration properties were analyzed. With increasing imidazolium (PIS)ratio, the PISPVAx blend membranes show phase separation between the hydrophobic and hydrophilic polymer chains, and thus, feature well-connected hydrophilic channels. The highest ionic conductivity of 89.7 mS cm?¹ was observed for the PISPVA46 membrane when using with 0.5 M KOH solution at 60 °C. The outstanding electrochemical performance of the PISPVA46 membrane, compared with those of PISPVA37 and PISPVA28, was reflected in a current density of 547.7 mA cm?² at a cell voltage of 2.0 V. The higher imidazole ratio in the blend membrane produced an increase in the elongation at break and hydration property, such as water uptake and IEC, that obviously enhances the ion conducting capability of the resulting AEMs. Additionally, the KOH molecules were introduced into the membrane through PVA, resulting in high KOH uptake. Therefore, the PISPVAx blend membranes are useful candidates for anion exchange membrane water electrolysis (AEMWE)systems.
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element WATER ELECTROLYSIS
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element ANION EXCHANGE MEMBRANE (AEM)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLY(1-BUTYL-3-VINYLIMIDAZOLE-CO-STYRENE)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element POLY(VINYL ALCOHOL)
650 14 - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical term or geographic name entry element IMIDAZOLIUM IONIC LIQUID
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Park, H. J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lee, S. Y.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lee, T. K.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Kim, H. J.
700 12 - ADDED ENTRY--PERSONAL NAME
Personal name Lee, Y. M.
856 40 - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier <a href="https://drive.google.com/file/d/1ktuKe2tl0x4fk7zXZpG69aSb91W7nLb1/view?usp=drivesdk">https://drive.google.com/file/d/1ktuKe2tl0x4fk7zXZpG69aSb91W7nLb1/view?usp=drivesdk</a>
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Source of classification or shelving scheme Clasificación local
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  Clasificación local     Ref1 CICY CICY Documento préstamo interbibliotecario 25.06.2025   B-20428 25.06.2025 25.06.2025 Documentos solicitados